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Volumn 106, Issue 10, 2002, Pages 2322-2327

Excited-state charge transfer dynamics of p-dimethylaminobenzonitrile in quadrupolar solvents

Author keywords

[No Author keywords available]

Indexed keywords

QUADRUPOLAR SOLVENTS;

EID: 0037075813     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp012991o     Document Type: Article
Times cited : (31)

References (62)
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    • note
    • Strictly speaking, toluene and dioxane are dipolar solvents because they have nonvanishing permanent dipole moments. However, due to their small magnitude (e.g., ∼0.3 D for toluene), we expect that their contribution to solvation is nearly insignificant compared to the quadrupole moments. This is confirmed by their low dielectric constants, i.e., 2.4 and 2.2 for toluene and dioxane, which are typical values for nondipolar solvents. In this context, we will refer to them as quadrupolar solvents.
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    • note
    • Though not shown here, the structures of the reaction free energy surface for dioxane are similar.
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