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edited by T. Dorfmuller and R. Pecora (Springer, Berlin)
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D. Kivelson, in Rotational Dynamics of Small and Macromolecules, 4th ed., edited by T. Dorfmuller and R. Pecora (Springer, Berlin, 1987), Vol. 293, p. 1.
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Kivelson, D.1
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R. C. Reid, J. M. Prausnitz, and B. E. Poling, The Properties of Gases and Liquids, 4th ed. (McGraw-Hill, New York, 1987).
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Reid, R.C.1
Prausnitz, J.M.2
Poling, B.E.3
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5
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85037494563
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note
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Due to the inaccuracy of hydrodynamic models, the experimental separation of dielectric contributions to the friction is often not clear-cut. See for example the discussion in Ref. 32.
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11
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36449002675
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See, for example, the summaries of various theories provided in: D. S. Alavi, R. S. Hartman, and D. H. Waldeck, J. Chem. Phys. 94, 4509 (1991); A. Papazyan and M. Maroncelli, ibid. 102, 2888 (1995).
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Alavi, D.S.1
Hartman, R.S.2
Waldeck, D.H.3
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12
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36449001348
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See, for example, the summaries of various theories provided in: D. S. Alavi, R. S. Hartman, and D. H. Waldeck, J. Chem. Phys. 94, 4509 (1991); A. Papazyan and M. Maroncelli, ibid. 102, 2888 (1995).
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J. Chem. Phys.
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Papazyan, A.1
Maroncelli, M.2
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25
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0030575232
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M. G. Kurnikova, D. H. Waldeck, and R. D. Coalson, J. Chem. Phys. 105, 628 (1996); M. G. Kurnikova, N. Balabai, D. H. Waldeck, and R. D. Coalson, J. Am. Chem. Soc. 120, 6121 (1998).
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J. Chem. Phys.
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Kurnikova, M.G.1
Waldeck, D.H.2
Coalson, R.D.3
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26
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0031748676
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M. G. Kurnikova, D. H. Waldeck, and R. D. Coalson, J. Chem. Phys. 105, 628 (1996); M. G. Kurnikova, N. Balabai, D. H. Waldeck, and R. D. Coalson, J. Am. Chem. Soc. 120, 6121 (1998).
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Kurnikova, M.G.1
Balabai, N.2
Waldeck, D.H.3
Coalson, R.D.4
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33
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85037511206
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note
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Bruehl and Hynes (Ref. 40) and Bursulaya et al. (Ref. 42) did examine this question in the rotational case, using a somewhat different definition of dielectric friction from the one applied here. Both studies reported only limited agreement between the dynamics of dipolar solvation and dielectric friction, similarly to what we observe here.
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47
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0001489826
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B. J. Berne, M. K. Tuckerman, J. E. Straub, and A. L. R. Bug, J. Chem. Phys. 93, 5084 (1990).
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Berne, B.J.1
Tuckerman, M.K.2
Straub, J.E.3
Bug, A.L.R.4
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49
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0029403121
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M. L. Horng, J. A. Gardecki, A. Papazyan, and M. Maroncelli, J. Phys. Chem. 99, 17311 (1995).
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Horng, M.L.1
Gardecki, J.A.2
Papazyan, A.3
Maroncelli, M.4
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51
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85037501896
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note
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The force parallel to the bond direction and the forces on the other solute atom (eq) behave similarly. The perpendicular component is convenient for display purposes due to its zero average value.
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53
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0001324374
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S. Koneshan, J. Rasaiah, R. Lynden-Bell, and S. Lee, J. Phys. Chem. B 102, 4193 (1998).
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J. Phys. Chem. B
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Koneshan, S.1
Rasaiah, J.2
Lynden-Bell, R.3
Lee, S.4
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55
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85037507909
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note
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We have simulated rotational friction on the polyatomic solute coumarin 153 in acetonitrile and methanol in much the same manner as described here for diatomic solutes. In this cases as well, the cross correlations between mechanical and dielectric components of the torque-torque correlation functions are comparable (and of the opposite sign) to the dielectric term in both acetonitrile and methanol.
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