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RhP = 120 Hz), in agreeement with the data reported in ref 14.
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2142714497
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note
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2) with MeI indicate that chelate ring opening and coordination of iodide is more facile in these complexes.
-
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43
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2142707211
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note
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31P NMR were hampered by the low solubility of 1a under these conditions.
-
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-
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44
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2142649208
-
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note
-
-1. The value of the ratio Abs(2a)/ Abs(1a) at 8 M MeI was therefore obtained by plotting A(2062)/A(1987) vs [MeI] and subtracting the y intercept of the linear plot from the measured value of A(2062)/A(1987) at 8 M MeI. This was then converted into a ratio of concentrations, [2a]/[1a], by dividing by 0.6 the ratio of extinction coefficients measured for the v(CO) bands of the Ir analogues 5a and 4a.
-
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45
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2142817148
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note
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In our preliminary communication of these results (ref 16) the influence of isomeric forms of 2b on the migratory insertion rate constant was neglected.
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46
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2142815735
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2142652132
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orth, is small (<1°) in both structures.
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55
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2142642240
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note
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HP couplings. This inequivalence is conferred by unsymmetrical coordination in the two axial sites, and will be maintained even if the ligand conformation is fluxional.
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62
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0001715710
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2142697185
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note
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-
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64
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2142805900
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note
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- after prolonged reaction.
-
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65
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0000823343
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See also ref 42
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3)(mnt)(COR)] (mnt = maleonitriledithiolate) (Cheng, C.-H.; Spivack, B. D.; Eisenberg, R. J. Am. Chem. Soc. 1977, 99, 3003. Cheng, C.-H.; Eisenberg, R. Inorg. Chem. 1979, 18, 2438).
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0030909008
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