Electronically and sterically induced structural distortions in square-planar d8 complexes

Organometallics

Volumn 19, Issue 18, 2000, Pages 3591-3596

  Rothlisberger, Ursula ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; PROBABILITY DENSITY FUNCTION; STRUCTURE (COMPOSITION); X RAY DIFFRACTION ANALYSIS;

DENSITY FUNCTIONAL THEORY; SQUARE PLANAR GEOMETRY; STRUCTURAL DISTORTION;

ORGANOMETALLICS;

EID: 0034274454     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000466q     Document Type: Article

References (6)

1. Shriver, D. F.; Atkins, P. W.; Langford, C, H. Inorganic Chemistry; Oxford University Press: Oxford, U.K., 1990; p 194.
2. Huheey, J. E. Inorganic Chemistry, 3rd ed.; Harper International SI: Cambridge, U.K., 1983; p 411.
3. Kerr, A.; Mardr, T. B.; Norman, N. C.; Orpen, A. G.; Quayle, M. J.; Rice, C. R.; Timms, P. L.; Whittell, G. R. Chem. Commun. 1998, 319.
4. Porzio, W.; Musco, A.; Immirzi, A. Inorg. Chem. 1980, 19, 2537.
5. 2 the P-Pd-P angle is ca. 174°;
6. see: Fraser, S. L.; Antipin, M. Y.; Khroustalyov, V. N.; Grushin, V. V. J. Am. Chem. Soc. 1997, 119, 4769-4770.