Double diastereoselective intramolecular cyclopropanation to P-chiral [3.1.0]-bicyclic phosphonates

Organic Letters

Volumn 4, Issue 14, 2002, Pages 2357-2360

  Moore, Joel D ^a   Sprott, Kevin T ^a   Wrobleski, Aaron D ^a   Hanson, Paul R ^a  

^a UNIVERSITY OF KANSAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPROPANE DERIVATIVE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; PHOSPHINE OXIDE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CATALYSIS; CRYSTALLOGRAPHY, X-RAY; CYCLIC P-OXIDES; CYCLOPROPANES; INDICATORS AND REAGENTS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; STEREOISOMERISM;

EID: 0037062895     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol026080o     Document Type: Article

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50. 3N and distilled under vacuum.
51. R diastereomer is demonstrated, coelution with the trans diastereomers during flash chromatography hinders facile purification (see Supporting Information).
52. See Supporting Information.