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Volumn 20, Issue 3, 2001, Pages 523-533

Mechanistic features of boron-iodine bond activation of B-iodocarboranes

Author keywords

[No Author keywords available]

Indexed keywords

BORON-IODINE BOND ACTIVATION; HALOARENES; IODOCARBORANES;

EID: 0035809298     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0008575     Document Type: Article
Times cited : (64)

References (106)
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    • note
    • 11)Cl], which has been characterized by elemental analysis (C, H, Cl, and P) and a melting point. Neither yield nor spectroscopic/structural data have been reported for the isolated material.
  • 56
    • 0011591146 scopus 로고    scopus 로고
    • note
    • 2] and alkali. As the latter may cause the degradation reaction of the carborane skeleton, we did not use this method.
  • 62
    • 0003080574 scopus 로고
    • note
    • 11 coordination. For a review of complexes of the type R-X-M (X = halogen), see: Kulawiec, R. J.; Crabtree, R. H. Coord. Chem. Rev. 1990, 99, 89.
    • (1990) Coord. Chem. Rev. , vol.99 , pp. 89
    • Kulawiec, R.J.1    Crabtree, R.H.2
  • 64
    • 0011530527 scopus 로고    scopus 로고
    • note
    • 31P NMR signal observed (δ = 21.6 ppm), which was not identified.
  • 79
    • 0001455450 scopus 로고    scopus 로고
    • note
    • 2Pd(I)Ar], which isomerize to the trans-isomer rapidly and quantitatively. Casado, A. L.; Espinet, P. Organometallics 1998, 17, 954.
    • (1998) Organometallics , vol.17 , pp. 954
    • Casado, A.L.1    Espinet, P.2
  • 80
    • 0011652942 scopus 로고
    • Palladium complexes containing a σ-B-carboranyl ligand have been reported
    • Palladium complexes containing a σ-B-carboranyl ligand have been reported. Kalinin, V. N.; Usatov, A. V.; Zakharkin, L. I. Metalloorg. Khim. 1989, 2, 54.
    • (1989) Metalloorg. Khim. , vol.2 , pp. 54
    • Kalinin, V.N.1    Usatov, A.V.2    Zakharkin, L.I.3
  • 90
    • 0011531064 scopus 로고    scopus 로고
    • note
    • + containing two aromatic substituents of different steric bulk arylate nucleophiles selectively wit the bulkier of the two aryls. This phenomenon is commonly observed when one of the aryls bears ortho substituent-(s), whereas the other one does not. The selective binding of a nucleophile to the ortho-substituted aryl is called "ortho-effect".
  • 91
    • 0003590357 scopus 로고
    • Patai, S., Rappoport, Z., Eds.; Wiley Interscience: Chichester
    • Koser, G. F. In The Chemistry of Functional Groups, Suppl. D; Patai, S., Rappoport, Z., Eds.; Wiley Interscience: Chichester, 1983; p 1173.
    • (1983) The Chemistry of Functional Groups, Suppl. D , pp. 1173
    • Koser, G.F.1
  • 93
    • 0011652944 scopus 로고    scopus 로고
    • note
    • Limited information has been accrued on molecular and crystal structures of monosubstituted B-iodocarboranes and B-carboranyl iodonium salts. In addition to the very early crystallographic studies of 9-iodo-o-carborane and 9-iodo-m-carborane, molecular and crystal structures of only few such compounds, namely, 2-iodo-p-carborane and o-carboran-9-yl(phenyl)iodonium iodide, have been published. Hawthorne and co-workers have also reported X-ray structures of a series of di- and polyiodinated carboranes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.