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2Pd(I)Ar], which isomerize to the trans-isomer rapidly and quantitatively. Casado, A. L.; Espinet, P. Organometallics 1998, 17, 954.
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80
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0011652942
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Palladium complexes containing a σ-B-carboranyl ligand have been reported
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90
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0011531064
-
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note
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+ containing two aromatic substituents of different steric bulk arylate nucleophiles selectively wit the bulkier of the two aryls. This phenomenon is commonly observed when one of the aryls bears ortho substituent-(s), whereas the other one does not. The selective binding of a nucleophile to the ortho-substituted aryl is called "ortho-effect".
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91
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0011652944
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Limited information has been accrued on molecular and crystal structures of monosubstituted B-iodocarboranes and B-carboranyl iodonium salts. In addition to the very early crystallographic studies of 9-iodo-o-carborane and 9-iodo-m-carborane, molecular and crystal structures of only few such compounds, namely, 2-iodo-p-carborane and o-carboran-9-yl(phenyl)iodonium iodide, have been published. Hawthorne and co-workers have also reported X-ray structures of a series of di- and polyiodinated carboranes.
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94
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97
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(a) Grushin, V. V.; Demkina, I. I.; Tolstaya, T. P.; Galakhov, M. V.; Bakhmutov, V. I. Metalloorg. Khim. 1989, 2, 727.
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