The trans influence of F, Cl, Br and I ligands in a series of square-planar Pd(II) complexes. Relative affinities of halide anions for the metal centre in trans-[(Ph3P)2Pd(Ph)X]

Inorganica Chimica Acta

Volumn 280, Issue 1-2, 1998, Pages 87-98

  Flemming, Jeffrey P ^a   Pilon, Mark C ^a   Borbulevitch, Oleg Ya ^b   Antipin, Mikhail Yu ^b   Grushin, Vladimir V ^a,c  

^a WILFRID LAURIER UNIVERSITY   (Canada)

^b A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^c DUPONT COMPANY   (United States)

Author keywords

Aryl complexes; Crystal structures; Halide complexes; Palladium complexes; Trans influence

Indexed keywords

BOND LENGTH; BROMINE; CHLORINE; CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; EQUILIBRIUM CONSTANTS; METAL HALIDES; SINGLE CRYSTALS; STYRENE;

ARYL COMPLEXES; DICHLOROCARBENE; ELECTRON-DONATING EFFECTS; HALIDE COMPLEXES; METAL CENTRES; PALLADIUM COMPLEXES; SINGLE-CRYSTAL X-RAY DIFFRACTION STUDIES; TRANS INFLUENCE;

PALLADIUM COMPOUNDS;

EID: 0002102195     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(98)00055-3     Document Type: Article

References (58)

1. N.M. Doherty, N.W. Hoffman, Chem. Rev. 91 (1991) 553.
2. M. Witt, H.W. Roesky, Prog. Inorg. Chem. 40 (1992) 353.
3. J.H. Holloway, E.G. Hope, J. Fluorine Chem. 76 (1996) 209.
4. J.L. Kiplinger, T.G. Richmond, C.E. Osterberg, Chem. Rev. 94 (1994) 373.
5. K. Leary, D.H. Templeton, A. Zalkin, N. Bartlett, Inorg. Chem. 12 (1973) 1726; E. Alter, Z. Anorg. Allg. Chem. 408 (1974) 115; A.F. Wright, B.E.F. Fender, N. Bartlett, K. Leary, Inorg. Chem. 17 (1978) 748; A. Tressaud, J.L. Soubeyroux, H. Touhara, G. Demazeau, F. Langlais, Mater. Res. Bull. 16 (1981) 207; B. Bachmann, B.G. Mueller, Z. Anorg. Allg. Chem. 597 (1991) 9.
6. K. Leary, D.H. Templeton, A. Zalkin, N. Bartlett, Inorg. Chem. 12 (1973) 1726; E. Alter, Z. Anorg. Allg. Chem. 408 (1974) 115; A.F. Wright, B.E.F. Fender, N. Bartlett, K. Leary, Inorg. Chem. 17 (1978) 748; A. Tressaud, J.L. Soubeyroux, H. Touhara, G. Demazeau, F. Langlais, Mater. Res. Bull. 16 (1981) 207; B. Bachmann, B.G. Mueller, Z. Anorg. Allg. Chem. 597 (1991) 9.
7. K. Leary, D.H. Templeton, A. Zalkin, N. Bartlett, Inorg. Chem. 12 (1973) 1726; E. Alter, Z. Anorg. Allg. Chem. 408 (1974) 115; A.F. Wright, B.E.F. Fender, N. Bartlett, K. Leary, Inorg. Chem. 17 (1978) 748; A. Tressaud, J.L. Soubeyroux, H. Touhara, G. Demazeau, F. Langlais, Mater. Res. Bull. 16 (1981) 207; B. Bachmann, B.G. Mueller, Z. Anorg. Allg. Chem. 597 (1991) 9.
8. K. Leary, D.H. Templeton, A. Zalkin, N. Bartlett, Inorg. Chem. 12 (1973) 1726; E. Alter, Z. Anorg. Allg. Chem. 408 (1974) 115; A.F. Wright, B.E.F. Fender, N. Bartlett, K. Leary, Inorg. Chem. 17 (1978) 748; A. Tressaud, J.L. Soubeyroux, H. Touhara, G. Demazeau, F. Langlais, Mater. Res. Bull. 16 (1981) 207; B. Bachmann, B.G. Mueller, Z. Anorg. Allg. Chem. 597 (1991) 9.
9. K. Leary, D.H. Templeton, A. Zalkin, N. Bartlett, Inorg. Chem. 12 (1973) 1726; E. Alter, Z. Anorg. Allg. Chem. 408 (1974) 115; A.F. Wright, B.E.F. Fender, N. Bartlett, K. Leary, Inorg. Chem. 17 (1978) 748; A. Tressaud, J.L. Soubeyroux, H. Touhara, G. Demazeau, F. Langlais, Mater. Res. Bull. 16 (1981) 207; B. Bachmann, B.G. Mueller, Z. Anorg. Allg. Chem. 597 (1991) 9.
10. S.L. Fraser, M.Yu. Antipin, V.N. Khroustalyov, V.V. Grushin, J. Am. Chem. Soc. 119 (1997) 4769.
11. J. Tsuji, Palladium Reagents and Catalysis: Innovations in Organic Synthesis, Wiley, Chichester, 1995.
12. T.G. Appleton, H.C. Clark, L.E. Manzer, Coord. Chem. Rev. 10 (1973) 335.
13. F.A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, Wiley, New York, 5th edn., 1988.
14. [ 10] Yu.N. Kukushkin, Chemistry of Coordination Compounds, Vysshaya Shkola, Moscow, 1985 (in Russian).
15. J. Howard, P. Woodward, J. Chem. Soc., DaltonTrans. (1973) 1840.
16. M.M. Brezinski, J. Schneider, L.J. Radonovich, K.J. Klabunde, Inorg. Chem. 28 (1989) 2414.
17. M.A. Cairns, K.R. Dixon, J.J. McFarland, J. Chem. Soc., Dalton Trans. (1975) 1159.
18. A. Domenicano, I. Hargittai (eds.), Accurate Molecular Structures: their Determination and Importance, Oxford University Press, New York, 1992.
19. J. Chatt, B.L. Shaw, J. Chem. Soc. (1959) 4020.
20. G.W. Parshall, J. Am. Chem. Soc. 88 (1966) 704.
21. R.P. Stewart, P.M. Treichel, J. Am. Chem. Soc. 92 (1970) 2710.
22. G.W. Parshall, J. Am. Chem. Soc. 96 (1974) 2360.
23. D.R. Coulson, J. Am. Chem. Soc. 98 (1976) 3111.
24. J.T. Poulton, K. Folting, W.E. Streib, K.G. Caulton, Inorg. Chem. 31 (1992) 3190.
25. J.T. Poulton, M.P. Sigalas, K. Folting, W.E. Streib, O. Eisenstein, K.G. Caulton, Inorg. Chem. 33 (1994) 1476.
26. J. Manna, C.J. Kuehl, J.A. Whiteford, P.J. Stang, Organometallics 16 (1997) 1897.
27. G. Klopman, in G. Klopman (ed.), Chemical Reactivity and Reaction Paths, Wiley, New York, 1974, p. 55.
28. K.G. Caulton, New J. Chem. 18 (1994) 25.
29. D.M. Branan, N.W. Hoffman, E.A. McElroy, N.C. Miller, D.L. Ramage, A.F. Schott, S.H. Young, Inorg. Chem. 26 (1987) 2915.
30. F. Araghizadeh, D.M. Branan, N.W. Hoffman, J.H. Jones, E.A. McElroy, N.C. Miller, D.L. Ramage, A.B. Salazar, S.H. Young, Inorg. Chem. 26 (1988) 3752.
31. (a) K.O. Christe, W.W. Wilson, R.D. Wilson, R. Bau, J. Feng, J. Am. Chem. Soc. 112 (1990) 7619;
32. (b) R. Schwesinger, R. Link, G. Thiele, H. Rotter, D. Honert, H.-H. Limbach, F. Männle, Angew. Chem., Int. Ed. Engl. 30 (1991) 1372;
33. K. Seppelt, Angew. Chem., Int. Ed. Engl. 31 (1992) 292;
34. K.M. Harmon, B.A. Southworth, K.E. Wilson, P.K. Keefer, J. Org. Chem. 58 (1993) 7294;
35. (e) R.Z. Gnann, R.I. Wagner, K.O. Christe, R. Bau, G.A. Olah, W.W. Wilson, J. Am. Chem. Soc. 119 (1997) 112;
36. (f) R.D. Chambers, W.K. Gray, S.R. Korn, Tetrahedron 51 (1995) 13 167 and Refs. therein.
37. R.K. Sharma, J.L. Fry, J. Org. Chem. 48 (1983) 2112; D. Landini, A. Maia, A. Rampoldi, J. Org. Chem. 54 (1989) 328; C. Rieux, B. Langlois, R. Gallo, C.R. Acad. Sci., Ser. 2 310 (1990) 25.
38. R.K. Sharma, J.L. Fry, J. Org. Chem. 48 (1983) 2112; D. Landini, A. Maia, A. Rampoldi, J. Org. Chem. 54 (1989) 328; C. Rieux, B. Langlois, R. Gallo, C.R. Acad. Sci., Ser. 2 310 (1990) 25.
39. R.K. Sharma, J.L. Fry, J. Org. Chem. 48 (1983) 2112; D. Landini, A. Maia, A. Rampoldi, J. Org. Chem. 54 (1989) 328; C. Rieux, B. Langlois, R. Gallo, C.R. Acad. Sci., Ser. 2 310 (1990) 25.
40. K.O. Christe, W.W. Wilson, J. Fluorine Chem. 47 (1990) 117.
41. V.V. Grushin, Angew. Chem., Int. Ed. Engl. 37 (1998) 994.
42. J.A. Riddick, W.B. Bunger, T.K. Sakano, Organic Solvents: Physical Properties and Methods of Purification, Wiley, New York, 4th edn, 1986, pp. 490-491.
43. S. Bekkevol, I. Svorstoel, H. Hoeiland, J. Songstad, Acta Chem. Scand. B 37 (1983) 935; J.C. Fanning, L.K. Keefer, J. Chem. Soc., Chem. Commun. (1987) 955.
44. S. Bekkevol, I. Svorstoel, H. Hoeiland, J. Songstad, Acta Chem. Scand. B 37 (1983) 935; J.C. Fanning, L.K. Keefer, J. Chem. Soc., Chem. Commun. (1987) 955.
45. B.K. Bennett, R.G. Harrison, T.G. Richmond, J. Am. Chem. Soc. 116 (1994) 11 165.
46. J.E. Veltheer, P. Burger, R.G. Bergman, J. Am. Chem. Soc. 117 (1995) 12 478.
47. [ 35 ] W.W. Dukat, J.H. Holloway, E.G. Hope, M.R. Rieland, P.J. Townson, R.L. Powell, J. Chem. Soc., Chem. Commun. (1993) 1429.
48. J.H. Holloway, E.G. Hope, P.J. Townson, R.L. Powell, J. Fluorine Chem. 76 (1996) 105.
49. S.T. Belt, M. Helliwell, W.D. Jones, M.G. Partridge, R.N. Perutz, J. Am. Chem. Soc. 115 (1993) 1429.
50. [ 38] E.V. Dehmlow, S.S. Dehmlow, Phase Transfer Catalysis, Verlag Chemie, Weinheim, 1983.
51. N.S. Zefirov, D.A. Makhon'kov, Chem. Rev. 82 (1982) 615.
52. A.G. Orpen, L. Brammer, F.H. Allen, O. Kennard, D.G. Watson, R. Taylor, J. Chem. Soc., Dalton Trans. (1989) S1-S83; Cambridge Crystallographic Data Bank, 12 Union Road, Cambridge CB2 1EZ, UK.
53. M.R. Churchill, Perspect. Struct. Chem. 3 (1970) 91.
54. A.G. Orpen, N.G. Connelly, J. Chem. Soc., Chem. Commun. (1985) 1310; G. Pacchioni, P.S. Bagus, Inorg. Chem. 31 (1992) 4391.
55. A.G. Orpen, N.G. Connelly, J. Chem. Soc., Chem. Commun. (1985) 1310; G. Pacchioni, P.S. Bagus, Inorg. Chem. 31 (1992) 4391.
56. I. Svorstoel, H. Hoeiland, J. Songstad, Acta Chem. Scand. B 38 (1984) 885.
57. W. Douglas, J.K. Ruff, J. Organomet. Chem. 65 (1974) 65.
58. P. Fitton, E.A. Rick, J. Organomet. Chem. 28 (1971) 287.