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Volumn 119, Issue 51, 1997, Pages 12441-12453

Mechanistic studies on the aryl-aryl interchange reaction of ArPdL2I (L = triarylphosphine) complexes

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; MOLECULAR INTERACTION; POLYMERIZATION;

EID: 0031585711     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja972554g     Document Type: Article
Times cited : (298)

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    • For examples of P-C cleavage in nickel compounds, see: (a) Green, M. L. H.; Simth, M. J.; Felkin, H.; Swierczewski, G. J. Chem. Soc., Chem. Commun. 1971, 158. (b) Nakamura, A.; Otsuka, S. Tetrahedron Lett. 1974, 463. (c) Reference 35f. (d) Reference 351.
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    • For examples of P-C cleavage in nickel compounds, see: (a) Green, M. L. H.; Simth, M. J.; Felkin, H.; Swierczewski, G. J. Chem. Soc., Chem. Commun. 1971, 158. (b) Nakamura, A.; Otsuka, S. Tetrahedron Lett. 1974, 463. (c) Reference 35f. (d) Reference 351.
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    • For examples of P-C cleavage in cobalt compounds, see: (a) Reference 35f. (b) Reference 351. (c) Sakatura, T.; Kobayashi, T.; Hayashi, T.; Kawabata, Y.; Tanaka, M.; Ogata, I. J. Organomet. Chem. 1984, 267, 171.
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    • (d) Reference 14d.
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    • 5]phenyl rings are negligible. A negligible isotope effect is in fact expected due to the at least two-bond separation between the reaction center and a perturbing isotope, as well as the geometry of the aryl ring, and is strongly confirmed by the fidelity of the experimental interchange distributions to the predicted distributions. For a discussion of secondary isotope effects, see: Carpenter, B. K., Determination of Organic Reaction Mechanisms; Wiley: New York, 1984; pp 96-100.
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