Synthesis of singly and doubly bridged ansa-Zirconocene hydrides. Formation of an unusual mixed valence trimeric hydride by reaction of H2 with {(Me2Si)2(η5- C5H3)2} Zr(CH3)2 and generation of a dinitrogen complex by reaction of N2 with a zirconocene dihydride

Organometallics

Volumn 20, Issue 3, 2001, Pages 534-544

  Chirik, Paul J ^a   Henling, Lawrence M ^a   Bercaw, John E ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANCILLARY LIGAND EFFECTS; METALLOCENE CHEMISTRY; MIXED VALENCE TRIMERIC HYDRIDE; ZIRCONOCENE HYDRIDES;

CHEMISTRY; HYDRIDES; HYDROGENATION; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL); TEMPERATURE; X RAY DIFFRACTION ANALYSIS;

ZIRCONIUM COMPOUNDS;

EID: 0035809267     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000739h     Document Type: Article

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54. Crystallographic data for the structures of 1 (CCDC 114738), 2 (CCDC 147896), 5 (CCDC 147897), and 11 (CCDC 110868) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publications. Copies of the data can be obtained on request, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44 1223 336033 or e-mail: deposit@ccdc.cam.ac.uk). Structure factors are available electronically: email: xray@caltech.edu.