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0342829142
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note
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2 = 0.116 (all data), residual electron density 0.84/ - 0.70 e Å 3. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-153429 (1) and CCDC-153430 (2). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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37
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0343699683
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note
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-1).
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38
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0343699684
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note
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In agreement with this assumption, a noticeable difference was observed in the solid-state CD spectra (Nujol paste) of 2 and 3, though their CD spectra in water are essentially identical; 2 exhibits a major negative CD band at 521 nm in the solid state, while the corresponding negative band of 3 appears at much longer wavelength of 551 nm.
-
-
-
-
39
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0342394420
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-
note
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As indicated by one of the referees, the solid-state structures of 1 and 2 would not be retained in solution; conversion to monomers and/or oligomers would result from cleavage of Ag-S and Ag-O bonds. This is suggested by the fact that the CD spectra of 1 and 2 in water are very similar to those of 4 and 5, respectively.
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