Enantioselective aggregation of cobalt (III) octahedrons in a one-dimensional S-bridged CoIIIAgI array that leads to spontaneous resolution

Chemistry Letters

Volumn , Issue 11, 2000, Pages 1258-1259

  Konno, Takumi ^a   Tokuda, Keiji ^a   Okamoto, Ken Ichi ^b   Hirotsu, Masakazu ^a  

^a GUNMA UNIVERSITY   (Japan)

^b UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034344671     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.1258     Document Type: Article

References (20)

1. M. J. Heeg, R. C. Elder, and E. Deutsch, Inorg. Chem., 18, 2036 (1979).
2. M. J. Heeg, R. C. Elder, and E. Deutsch, Inorg. Chem., 19, 554 (1980).
3. T. Konno and K. Okamoto, Inorg. Chem., 36, 1403 (1997); T. Konno, T. Machida, and K. Okamoto, Bull. Chem. Soc. Jpn., 71, 175 (1998); K. Okamoto, C. Sasaki, Y. Yamada, and T. Konno, Bull. Chem. Soc. Jpn., 72, 1685 (1999); K. Tokuda, K. Okamoto, and T. Konno, Inorg. Chem., 39, 333 (2000); T. Konno, M. Hattori, T. Yoshimura, and M. Hirotsu, Chem. Lett., 2000, 853.
4. T. Konno and K. Okamoto, Inorg. Chem., 36, 1403 (1997); T. Konno, T. Machida, and K. Okamoto, Bull. Chem. Soc. Jpn., 71, 175 (1998); K. Okamoto, C. Sasaki, Y. Yamada, and T. Konno, Bull. Chem. Soc. Jpn., 72, 1685 (1999); K. Tokuda, K. Okamoto, and T. Konno, Inorg. Chem., 39, 333 (2000); T. Konno, M. Hattori, T. Yoshimura, and M. Hirotsu, Chem. Lett., 2000, 853.
5. T. Konno and K. Okamoto, Inorg. Chem., 36, 1403 (1997); T. Konno, T. Machida, and K. Okamoto, Bull. Chem. Soc. Jpn., 71, 175 (1998); K. Okamoto, C. Sasaki, Y. Yamada, and T. Konno, Bull. Chem. Soc. Jpn., 72, 1685 (1999); K. Tokuda, K. Okamoto, and T. Konno, Inorg. Chem., 39, 333 (2000); T. Konno, M. Hattori, T. Yoshimura, and M. Hirotsu, Chem. Lett., 2000, 853.
6. T. Konno and K. Okamoto, Inorg. Chem., 36, 1403 (1997); T. Konno, T. Machida, and K. Okamoto, Bull. Chem. Soc. Jpn., 71, 175 (1998); K. Okamoto, C. Sasaki, Y. Yamada, and T. Konno, Bull. Chem. Soc. Jpn., 72, 1685 (1999); K. Tokuda, K. Okamoto, and T. Konno, Inorg. Chem., 39, 333 (2000); T. Konno, M. Hattori, T. Yoshimura, and M. Hirotsu, Chem. Lett., 2000, 853.
7. T. Konno and K. Okamoto, Inorg. Chem., 36, 1403 (1997); T. Konno, T. Machida, and K. Okamoto, Bull. Chem. Soc. Jpn., 71, 175 (1998); K. Okamoto, C. Sasaki, Y. Yamada, and T. Konno, Bull. Chem. Soc. Jpn., 72, 1685 (1999); K. Tokuda, K. Okamoto, and T. Konno, Inorg. Chem., 39, 333 (2000); T. Konno, M. Hattori, T. Yoshimura, and M. Hirotsu, Chem. Lett., 2000, 853.
8. L. E. Asher and E. Deutsch, Inorg. Chem., 12, 1774 (1973); D. L. Nosco and E. Deutsch, Inorg. Synth., 21, 19 (1982).
9. L. E. Asher and E. Deutsch, Inorg. Chem., 12, 1774 (1973); D. L. Nosco and E. Deutsch, Inorg. Synth., 21, 19 (1982).
10. -1)]: 20.37 (2.48), 27.5 (2.8 sh), 35.19 (4.42).
11. w) = 0.051 (0.053) for 3230 reflections with I > 2.0σ(I).
12. 2O: C, 12.51; H,4.20; N, 12.16%. Found: C, 12.44; H, 4.24; N, 12.08%.
13. -1)]: 20.24 (2.22), 27.7 (2.6 sh), 35.01 (4.13).
14. w) = 0.033 (0.033) for 1902 reflections with I > 2.0σ(I).
15. 2) distance, while there is a marked difference in the averaged Ag-S bond distances (ca. 0.14 Å) between the two-coordinated and three-coordinated Ag atoms. T. Konno and K. Okamoto, Inorg. Chem., 36, 1403 (1997).
16. 2+structures, respectively.
17. H. D. Flack, Acta Crystallogr., Sect. A, 39, 876 (1983); H. D. Flack and G. Bernandinello, Acta Ctystallogr., Sect. A, 41, 500 (1985). Flack parameters refined for the Λ and Δ structures give the values 0.07(6) and 0.93(6), respectively, suggesting that the former is the correct choice.
18. H. D. Flack, Acta Crystallogr., Sect. A, 39, 876 (1983); H. D. Flack and G. Bernandinello, Acta Ctystallogr., Sect. A, 41, 500 (1985). Flack parameters refined for the Λ and Δ structures give the values 0.07(6) and 0.93(6), respectively, suggesting that the former is the correct choice.
19. 2O: C, 12.82; H, 4.66; N, 12.46; Co, 10.48; Ag, 9.59%. Found: C, 12.68; H, 4.84; N, 12.22; Co, 10.72; Ag, 9.72%.
20. J. Jacques, A. Collet, and S. H. Wilen, in "Enantiomers, Racemates and Resolutions," John Wiley & Sons Ltd., New York (1981).