Solvolysis of [B(C6H5)4]- in Methanol to Give the Chiral Coordination Polymer Cd(tcm)[B(OMe)4] · xMeOH, x ≈ 1.6

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 6, 1997, Pages 636-637

  Batten, Stuart R ^a   Hoskins, Bernard F ^a   Robson, Richard ^a  

^a UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

Boron; Bridging ligands; Cadmium; Coordination polymers; Tricyanomethanide

Indexed keywords

EID: 0030999177     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199706361     Document Type: Article

References (10)

1. K. R. Dunbar, Angew. Chem. 1996, 108, 1769; Angew. Chem. Int. Ed. Engl. 1996, 35, 1659.
2. K. R. Dunbar, Angew. Chem. 1996, 108, 1769; Angew. Chem. Int. Ed. Engl. 1996, 35, 1659.
3. S. R. Batten, B. F. Hoskins, R. Robson, J. Chem. Soc. Chem. Commun. 1991, 445, and unpublished results.
4. J. Konnert, D. Britton, Inorg. Chem. 1966, 5, 1193.
5. D. A. Bardwell, J. C. Jeffery, M. D. Ward, Inorg. Chim. Acta 1996, 241, 125.
6. D. A. Bardwell, J. C. Jeffery, M. D. Ward, University of Bristol (UK), personal communication.
7. w = 0.0395 for the 1497 observed reflections [I ≥ 3σ(I)]. To determine the absolute configuration, a refinement was carried out in SHELXL-93. A value of -0.03 (± 0.12) was obtained for the Flack parameter, which indicated that the correct configuration had been obtained. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-160. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223) 336-033; e-mail: deposit@chemcryst.cam.ac.uk).
8. M. Fujita, Y. J. Kwon, M. Miyazawa, K. Ogura, J. Chem. Soc. Chem. Commun. 1994, 1977.
9. K. D. Matthews, I. A. Kahwa, Inorg. Chem. 1993, 32, 1442.
10. 522.