Convergent syntheses of the enantiomeric CD- and JK-ring parts of ciguatoxin

Synlett

Volumn , Issue 5, 2001, Pages 691-693

  Fujiwara, Kenshu ^a   Takaoka, Daisuke ^a   Kusumi, Kensuke ^a   Kawai, Kentaro ^a   Murai, Akio ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Acyl anion equivalent; Ciguatoxin; Convergent synthesis; Dithioacetal mono S oxide; Reductive etherification

Indexed keywords

ACETAL DERIVATIVE; ALDEHYDE DERIVATIVE; CIGUATOXIN; KETONE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CYCLIZATION; ENANTIOMER; REACTION ANALYSIS; REDUCTION; TOXIN SYNTHESIS;

EID: 0035039187     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2001-13387     Document Type: Article

References (46)

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41. 3 [M]: 210.1256, found: 210.1264.
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46. H8-H9 value (9.3 Hz). Existence of NOE between H7/H9 proved that the stereochemistry at C7 was unchanged under the final reductive cyclization conditions (Figure 2). Formula Represented Figure 2