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Volumn , Issue 9, 1997, Pages 845-846

Stereoselective synthesis of the LM ring moiety of ciguatoxin: Reagent control of asymmetric dihydroxylation

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EID: 0031317275     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.845     Document Type: Article
Times cited : (37)

References (24)
  • 17
    • 33947469257 scopus 로고
    • The stereochemistry was determined by conversion of 5 into (S,S)-2,3-dimethylbutane-1,4-diol: G. E. McCasland and S. Proskow, J. Am. Chem. Soc., 78, 5646 (1956).
    • (1956) J. Am. Chem. Soc. , vol.78 , pp. 5646
    • McCasland, G.E.1    Proskow, S.2
  • 19
    • 0040159405 scopus 로고    scopus 로고
    • note
    • Intermediary of epoxide was supported by isolation without the subsequent acid treatment.
  • 20
    • 0040159406 scopus 로고    scopus 로고
    • note
    • The stereochemistry of 7, 9, and 10 was determined by NOE experiments. (formula presented)
  • 23
    • 0038975186 scopus 로고    scopus 로고
    • ref. 2c
    • The stereoselectivity due to substrate control appears to vary with the size of reagent. Related phenomena have been observed: see ref. 2c and T. Oishi, T. Iwakuma, M. Hirama, and S. Itô, Synlett, 1995, 404.
    • Synlett , vol.1995 , pp. 404
    • Oishi, T.1    Iwakuma, T.2    Hirama, M.3    Itô, S.4
  • 24
    • 0038975188 scopus 로고    scopus 로고
    • note
    • 3) δ 13.65, 15.87, 40.56, 41.87, 45.68, 61.96, 70.68, 71.94, 74.40, 109.21, (TIPS group was omitted).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.