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Studies done with VSG proteins have shown that a trisaccharide can substitute for an α helix: Blum, M. L.; Down, J. A.; Gurnett, A. M.; Carrington, M.; Turner, M. J.; Wiley, D. C. Nature 1993, 362, 603-609.
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(b) The conformation of the trisaccharide portion of Aclacinomycin A is also consistent with this observation: Yang, D.; Wang, A. H. J. Biochemistry 1994,33,6595-6604.
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0029874823
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33847563666
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This result suggests that the primary pathway for polymerization of these substrates involves activation of the anomeric sulfide with phenylsulfenyl Inflate (Pathway 2, Scheme 2)
-
This result suggests that the primary pathway for polymerization of these substrates involves activation of the anomeric sulfide with phenylsulfenyl Inflate (Pathway 2, Scheme 2).
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40
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0016784439
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33847546612
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Indirect chemical referencing was done using chemical shift referencing ratios obtained from the following: www.bmrb.\visc.edu/ref_info/cshift.html
-
-
-
-
59
-
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33847562114
-
-
Assignments are reported to ±0.005 ppm accuracy. For the internal sugars B, C, and D overlap of resonances upon complexation to DNA made it difficult to measure chemical shift changes
-
Assignments are reported to ±0.005 ppm accuracy. For the internal sugars B, C, and D overlap of resonances upon complexation to DNA made it difficult to measure chemical shift changes.
-
-
-
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