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0343017356
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note
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CAUTION: Perchlorate salts of metal complexes with organic ligands are potentially explosive. Only small amounts of material should be prepared, and these should be handled with great care.
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28
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0343452971
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note
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Characterization data for all new ligands and complexes is provided in the Supporting Information.
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29
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37049096497
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Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
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0343888752
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note
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A weakly coordinated MeOH molecule (Cd-O(1), 2.54 Å) that is present in 50% occupancy has been omitted for clarity.
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32
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0343017346
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note
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1H NMR analysis of the reaction mixture after this time showed only the presence of unreacted bmppa.
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33
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0343452958
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note
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2 (1) also initiates amide alcoholysis.
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34
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0342583046
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note
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1H NMR revealed only the presence of unaltered bmppa (98% yield).
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35
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0343017347
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note
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+. No isotopic envelopes of greater than 3% intensity were observed in the region above m/z 500.
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