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Volumn 33, Issue 21, 2000, Pages 7776-7785

The importance of macroligand molecular weight and solvent polarity in modulating metal core reactivity in heteroleptic polymeric ruthenium tris(bipyridine) complex synthesis

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; CHELATION; FREE RADICAL POLYMERIZATION; HALOGENATION; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; ORGANIC SOLVENTS; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY;

EID: 0034297186     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma000837e     Document Type: Article
Times cited : (27)

References (74)
  • 2
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    • Sauvage, J.-P., Hosseini, M. W., Volume Eds.; Eisevier: Oxford, England, 1996; Vol. 9, Chapter 1; pp 1-42.
    • Sauvage, J.-P., Hosseini, M. W., Volume Eds.; Eisevier: Oxford, England, 1996; Vol. 9, Chapter 1; pp 1-42.
  • 6
  • 9
    • 0000295129 scopus 로고    scopus 로고
    • J.-P., Hosseini, M. W., Volume Eds.; Elsevier: Oxford, England, Chapter 5
    • Baxter, P. N. W. In Comprehensive Supramolecular Chemistry; Sauvage, J.-P., Hosseini, M. W., Volume Eds.; Elsevier: Oxford, England, 1996; Vol. 9, Chapter 5; pp 165-211.
    • (1996) Comprehensive Supramolecular Chemistry; Sauvage , vol.9
    • Baxter, P.N.W.1
  • 50
    • 85037461689 scopus 로고    scopus 로고
    • note
    • The 1H NMR spectra of polymeric complexes are indistinguishable, with resonances corresponding to polystyrene predominating. Core bpy protons are not evident. 'H NMR (300 MHz, CDC13): ô7.2-6.9 (br m, -Caffs), 6.7-6.3 (br m, -CeHs), 2.1-1.2 (br m, -CHPhCH2-). Exceptions are indicated for the respective complexes.
  • 51
    • 85037472340 scopus 로고    scopus 로고
    • The reported yield is corrected for aliquot removal.
    • The reported yield is corrected for aliquot removal.
  • 52
    • 85037470689 scopus 로고    scopus 로고
    • Molecular weight and UV/vis data for this product are provided in Table 3.
    • Molecular weight and UV/vis data for this product are provided in Table 3.
  • 53
    • 85037460017 scopus 로고    scopus 로고
    • Molecular weight and UV/vis data for this product are provided in Table 4.
    • Molecular weight and UV/vis data for this product are provided in Table 4.
  • 63
    • 0032095224 scopus 로고    scopus 로고
    • Kelch, S.; Rehahn, M. Macromolecules 1998, 31, 4102. Dissolution of this reagent in MeOH/H2U resulted in a color change from red to the dark purple indicative of the Ru(bpy)2Cl2 species.
    • (1998) Macromolecules , vol.31 , pp. 4102
    • Kelch, S.1    Rehahn, M.2
  • 74
    • 0006333956 scopus 로고
    • Solvent and Non-Solvents for Polymers
    • Brandrup, J., Immergut, E. H., Eds.; John Wiley and Sons: New York
    • Fuchs, O. Solvent and Non-Solvents for Polymers. In Polymer Handbook, 3rd ed.; Brandrup, J., Immergut, E. H., Eds.; John Wiley and Sons: New York, 1989; p VII/379.
    • (1989) Polymer Handbook, 3rd Ed. , pp. 379
    • Fuchs, O.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.