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When the ionic population of a mixed valent redox polymer is immobilized, the electron hopping reaction rate can be characterized in terms of the applied electric field and depends exponentially on the applied voltage bias.
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1842380251
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note
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15b indicates that redox couple formal potentials do not differ significantly between polyether and acetonitrile solvents.
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1842305153
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1842278285
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1842355248
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note
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-1; these values are only about 2-fold larger than those reported here.
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