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Volumn 104, Issue 34, 2000, Pages 8182-8191

A steady-state kinetic model can be used to describe the growth of self-assembled monolayers (SAMs) on gold

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ADSORPTION; CHEMISORPTION; CRYSTALLINE MATERIALS; ELLIPSOMETRY; GOLD; GONIOMETERS; INFRARED SPECTROSCOPY; REACTION KINETICS; SEMICONDUCTOR GROWTH;

EID: 0034246992     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp000650p     Document Type: Article
Times cited : (29)

References (59)
  • 34
    • 33645939441 scopus 로고    scopus 로고
    • The optimized C-S-S-C dihedral angles for the cyclic disulfides and the maximum distance spanned by the sulfur atoms of the chelating dithiol were determined by molecular modeling using PC Model V 5.0: Serena Software, Bloomington, IN
    • The optimized C-S-S-C dihedral angles for the cyclic disulfides and the maximum distance spanned by the sulfur atoms of the chelating dithiol were determined by molecular modeling using PC Model V 5.0: Serena Software, Bloomington, IN.
  • 35
    • 84990149346 scopus 로고
    • Contact angles of hexadecane are remarkably sensitive to the composition, structure, and molecular orientation of hydrocarbon interfaces: Bain, C. D.; Whitesides, G. M. Angew. Client., Int. Ed. Engl. 1989, 28, 506.
    • (1989) Angew. Client., Int. Ed. Engl. , vol.28 , pp. 506
    • Bain, C.D.1    Whitesides, G.M.2
  • 45
    • 33645903438 scopus 로고    scopus 로고
    • University of Houston, Houston, TX. Unpublished observations
    • Shon, Y.-S.; Lee, T. R. University of Houston, Houston, TX. Unpublished observations.
    • Shon, Y.-S.1    Lee, T.R.2
  • 46
    • 85087999532 scopus 로고    scopus 로고
    • cH2; values were checked on several different slides for immersion times ≥1 h. All measurements consistently showed higher crystallinities for the SAMs absorbed from ethanol, thereby excluding influence from instrumental error.
    • cH2; values were checked on several different slides for immersion times ≥1 h. All measurements consistently showed higher crystallinities for the SAMs absorbed from ethanol, thereby excluding influence from instrumental error.
  • 47
    • 33645917262 scopus 로고    scopus 로고
    • For example, it is possible that, relative to isooctane, ethanol destabilizes the physisorbed state (vide infra). In this scenario, alkanethiols might chemisorb directly (and thus rapidly) from ethanol without requiring the intermediacy of a physisorption preequilibrium.
    • For example, it is possible that, relative to isooctane, ethanol destabilizes the physisorbed state (vide infra). In this scenario, alkanethiols might chemisorb directly (and thus rapidly) from ethanol without requiring the intermediacy of a physisorption preequilibrium.
  • 53
    • 33645915968 scopus 로고    scopus 로고
    • note
    • Although data from the coadsorption of d-C17 and n-C17 might offer further insight to these discussions, the indistinguishable thicknesses, wettabilities, and IR spectra of the SAMs derived from these two adsorbates presently precludes this type of study.
  • 55
    • 33645947539 scopus 로고    scopus 로고
    • In coadsorption studies involving m-C17 and d-C17, it is possible that H1-C17 adsorbs preferentially as a kinetically trapped species. The exchange experiments involving preformed SAMs and free thiols in solution (see ref 52), however, argue against this hypothesis.
    • In coadsorption studies involving m-C17 and d-C17, it is possible that H1-C17 adsorbs preferentially as a kinetically trapped species. The exchange experiments involving preformed SAMs and free thiols in solution (see ref 52), however, argue against this hypothesis.
  • 57
    • 33645928481 scopus 로고    scopus 로고
    • note
    • 57
  • 59
    • 33645905951 scopus 로고    scopus 로고
    • Syracuse University, Syracuse, NY. Personal communication
    • Lees, W. J. Syracuse University, Syracuse, NY. Personal communication.
    • Lees, W.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.