Synthesis, structure, and fluxionality of (μ-diphenylsilylene) (fulvalene)tetracarbonyldirhenium - double Si-H activation to the first fulvalene silylene complex

Organometallics

Volumn 19, Issue 12, 2000, Pages 2389-2392

  Kayser, Bernd ^a   Eichberg, Michael J ^a   Vollhardt, K Peter C ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; HYDROGEN; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLYSIS; SILANES; SILICON; SYNTHESIS (CHEMICAL); X RAY ANALYSIS;

FLUXIONALITY; FULVALENEHEXACARBONYLDIRHENIUM; SILYLENE FULVALENEDIMETAL COMPLEX; SOLUTION DYNAMICS;

ORGANOMETALLICS;

EID: 0033700611     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000022u     Document Type: Article

References (63)

1. (a) Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175.
2. (b) Gauvin, F.; Harrod, J. F.; Woo, H. G. Adv. Organomet. Chem. 1998, 42, 363.
3. (c) Pannell, K. H.; Sharma, H. K. Chem. Rev. 1995, 95, 1351.
4. (d) Lickiss, P. D. Chem. Soc. Rev. 1992, 271.
5. (e) Zybill, C. Top. Curr. Chem. 1991, 160, 1.
6. (f) Tilley, T. D. In The Silicon-Heterroatom Bond; Patai, S., Rappoport, Z., Eds.; Wiley: New York, 1991; Chapters 9 and 10, pp 245, 309.
7. (g) Tilley, T. D. Comments Inorg. Chem. 1990, 10, 37.
8. (h) Tilley, T. D. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: New York, 1989; Chapter 24, p 1415.
9. (i) Curtis, M. D.; Epstein, P. S. Adv. Organomet. Chem. 1981, 19, 213.
10. Ogino, H.; Tobita, H. Adv. Organomet. Chem. 1998, 42, 223.
11. See, inter alia: (a) Vollhardt, K. P. C.; Cammack, J. K.; Matzger, A. J.; Bauer, A.; Capps, K. B.; Hoff, C. D. Inorg. Chem. 1999, 38, 2624. (b) Boese, R.; Cammack, J. K.; Matzger, A. J.; Pflug, K.; Tolman, W. B.; Vollhardt, K. P. C.; Weidman, T. W. J. Am. Chem. Soc. 1997, 119, 6757. (c) Tilset, M.; Vollhardt, K. P. C.; Boese, R. Organometallics 1994, 13, 3146. (d) McGovern, P. A.; Vollhardt, K. P. C. Synlett 1990, 493.
12. See, inter alia: (a) Vollhardt, K. P. C.; Cammack, J. K.; Matzger, A. J.; Bauer, A.; Capps, K. B.; Hoff, C. D. Inorg. Chem. 1999, 38, 2624. (b) Boese, R.; Cammack, J. K.; Matzger, A. J.; Pflug, K.; Tolman, W. B.; Vollhardt, K. P. C.; Weidman, T. W. J. Am. Chem. Soc. 1997, 119, 6757. (c) Tilset, M.; Vollhardt, K. P. C.; Boese, R. Organometallics 1994, 13, 3146. (d) McGovern, P. A.; Vollhardt, K. P. C. Synlett 1990, 493.
13. See, inter alia: (a) Vollhardt, K. P. C.; Cammack, J. K.; Matzger, A. J.; Bauer, A.; Capps, K. B.; Hoff, C. D. Inorg. Chem. 1999, 38, 2624. (b) Boese, R.; Cammack, J. K.; Matzger, A. J.; Pflug, K.; Tolman, W. B.; Vollhardt, K. P. C.; Weidman, T. W. J. Am. Chem. Soc. 1997, 119, 6757. (c) Tilset, M.; Vollhardt, K. P. C.; Boese, R. Organometallics 1994, 13, 3146. (d) McGovern, P. A.; Vollhardt, K. P. C. Synlett 1990, 493.
14. See, inter alia: (a) Vollhardt, K. P. C.; Cammack, J. K.; Matzger, A. J.; Bauer, A.; Capps, K. B.; Hoff, C. D. Inorg. Chem. 1999, 38, 2624. (b) Boese, R.; Cammack, J. K.; Matzger, A. J.; Pflug, K.; Tolman, W. B.; Vollhardt, K. P. C.; Weidman, T. W. J. Am. Chem. Soc. 1997, 119, 6757. (c) Tilset, M.; Vollhardt, K. P. C.; Boese, R. Organometallics 1994, 13, 3146. (d) McGovern, P. A.; Vollhardt, K. P. C. Synlett 1990, 493.
15. (a) Rausch, M. D.; Spink, W. C.; Conway, B. G.; Rogers, R. D.; Atwood, J. L. J. Organomet. Chem. 1990, 383, 227.
16. (b) Nesmeyanov, A. N.; Kolobova, N. E.; Anisimov, K. N.; Makarov, Yu. V. Izv. Akad. Nauk SSSR, Ser. Khim. 1969, 357.
17. Herberhold, M.; Biersack, M.; Bitterwolf, T. E.; Rheingold, A. L. Z. Naturforsch. 1993, 48B, 161.
18. Connor, J. M. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 6, Chapter 9 (Low Valent Organorhenium Compounds), p 167.
19. (a) Dong, D. F.; Hoyano, J. K.; Graham, W. A. G. Can. J. Chem. 1981, 59, 1455.
20. (b) Hoyano, J. K.; Graham, W. A. G. Organometallics 1982, 1, 783.
21. Sakaba, H.; Ishida, K.; Horino, H. Chem. Lett. 1998, 149.
22. Smith, R. A.; Bennett, M. J. Acta Crystallogr. 1977, B33, 1113.
23. Foust, A. S.; Hoyano, J. K.; Graham, W. A. G. J. Organomet. Chem. 1971, 32, C65.
24. Casey, C. P.; Cariño, R. S.; Sakaba, H.; Hayashi, R. K. Organometallics 1996, 15, 2640.
25. Casey, C. P.; Sakaba, H.; Hazin, P. N.; Powell, D. R. J. Am. Chem. Soc. 1991, 113, 8165.
26. Casey, C. P.; Cariño, R. S.; Hayashi, R. K.; Schladetzky, K. D. J. Am. Chem. Soc. 1996, 118, 1617.
27. Godoy, F.; Higgitt, C. L.; Klahn, A. H.; Oelckers, B.; Parsons, S.; Perutz, R. N. J. Chem. Soc., Dalton Trans. 1999, 2039.
28. (a) Malisch, W.; Hindahl, K.; Käb, H.; Reising, J.; Adam, W.; Prechtl, F. Chem. Ber. 1995, 128, 963.
29. (b) Tobita, H.; Shinagawa, I.; Ohnuki, S.; Abe. M.; Izumi, H.; Ogino, H. J. Organomet. Chem. 1994, 473, 187.
30. (a) Rosenberg, L.; Fryzuk, M. D.; Rettig, S. J. Organometallics 1999, 18, 958.
31. (b) Fryzuk, M. D.; Rosenberg, L.; Rettig, S. J. Organometallics 1996, 15, 2871.
32. (c) Wang, W.-D.; Eisenberg, R. J. Am. Chem. Soc. 1990, 112, 1833.
33. (d) Suzuki, H.; Takao, T.; Tanaka, M.; Morooka, Y. J. Chem. Soc., Chem. Commun. 1992, 476.
34. Kim, Y.-J.; Lee, S.-C.; Park, J.-I.; Osakada, K.; Choi, J.-C.; Yamamoto, T. Organometallics 1998, 17, 4929.
35. Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917.
36. See, inter alia: (a) Campion, B. K.; Heyn, R. H.; Tilley, T. D. Organometallics 1992, 11, 3918. (b) Tobita, H.; Kawano, Y.; Ogino, H. Chem. Lett. 1989, 2155. For a particularly relevant Ge analogue, see: (c) Job, R. C.; Curtis, M. D. Inorg. Chem. 1973, 12, 2514.
37. See, inter alia: (a) Campion, B. K.; Heyn, R. H.; Tilley, T. D. Organometallics 1992, 11, 3918. (b) Tobita, H.; Kawano, Y.; Ogino, H. Chem. Lett. 1989, 2155. For a particularly relevant Ge analogue, see: (c) Job, R. C.; Curtis, M. D. Inorg. Chem. 1973, 12, 2514.
38. See, inter alia: (a) Campion, B. K.; Heyn, R. H.; Tilley, T. D. Organometallics 1992, 11, 3918. (b) Tobita, H.; Kawano, Y.; Ogino, H. Chem. Lett. 1989, 2155. For a particularly relevant Ge analogue, see: (c) Job, R. C.; Curtis, M. D. Inorg. Chem. 1973, 12, 2514.
39. (a) McDonald, R.; Cowie, M. Organometallics 1990, 9, 2468. For a seminal study of a Ge analogue, see:
40. (b) Adams, R. D.; Cotton, F. A. J. Am. Chem. Soc. 1970, 92, 5003.
41. (a) Kawano, Y.; Tobita, H.; Shimoi, M.; Ogino, H. J. Am. Chem. Soc. 1994, 116, 8575.
42. (b) Ueno, K.; Hamashima, N.; Ogino, H. Organometallics 1992, 11, 1435.
43. (c) Kawano, Y.; Tobita, H.; Ogino, H. Organometallics 1992, 11, 499.
44. (d) Ueno, K.; Hamashima, N.; Shimoi, M.; Ogino, H. Organometallics 1991, 10, 959.
45. (e) Malisch, W.; Ries, W. Angew. Chem., Int. Ed. Engl. 1978, 17, 120. For a relevant early study of a related Ge compound, see:
46. (f) Adams, R. D.; Brice, M. D.; Cotton, F. A. Inorg. Chem. 1974, 13, 1080.
47. Braun, S.; Kalinowski, H.-O.; Berger, S. 100 and More Basic NMR Experiments; VCH: Weinheim, Germany, 1996; p 120.
48. Lewis, L. N.; Caulton, K. G. Inorg. Chem. 1981, 20, 1139.
49. For recent references, see: (a) Arnold, F. P. A., Jr. Organometallics 1999, 18, 4800. (b) Ueno, K.; Masuko, A.; Ogino, H. Organometallics 1999, 18, 2694. (c) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D. Organometallics 1998, 17, 5607. (d) Wada, H.; Tobita, H.; Ogino, H. Chem. Lett. 1998, 993.
50. For recent references, see: (a) Arnold, F. P. A., Jr. Organometallics 1999, 18, 4800. (b) Ueno, K.; Masuko, A.; Ogino, H. Organometallics 1999, 18, 2694. (c) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D. Organometallics 1998, 17, 5607. (d) Wada, H.; Tobita, H.; Ogino, H. Chem. Lett. 1998, 993.
51. For recent references, see: (a) Arnold, F. P. A., Jr. Organometallics 1999, 18, 4800. (b) Ueno, K.; Masuko, A.; Ogino, H. Organometallics 1999, 18, 2694. (c) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D. Organometallics 1998, 17, 5607. (d) Wada, H.; Tobita, H.; Ogino, H. Chem. Lett. 1998, 993.
52. For recent references, see: (a) Arnold, F. P. A., Jr. Organometallics 1999, 18, 4800. (b) Ueno, K.; Masuko, A.; Ogino, H. Organometallics 1999, 18, 2694. (c) Grumbine, S. K.; Mitchell, G. P.; Straus, D. A.; Tilley, T. D. Organometallics 1998, 17, 5607. (d) Wada, H.; Tobita, H.; Ogino, H. Chem. Lett. 1998, 993.
53. Hoffmann, R.; Minkin, V. I.; Carpenter, B. K. Bull. Soc. Chim. Fr. 1996, 133, 117.
54. Drage, J. S.; Vollhardt, K. P. C. Organometallics 1986, 5, 280.
55. Herrmann, W. A.; Andrejewski, D.; Herdtweck, E. J. Organomet. Chem. 1987, 319, 183.
56. SMART Area Detection Software Package; Siemens Industrial Automation Inc.: Madison, WI, 1995.
57. SAX Area Detector Integration Program, version 4.024; Siemens Industrial Automation, Inc., Madison, WI, 1995.
58. XPREP, version 5.03: Part of the SHELXTL Crystal Structure Determination Package; Siemens Industrial Automation, Inc., Madison, WI, 1995.
59. Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Polidori, G. J. Appl. Crystallogr. 1993, 26, 343.
60. Cromer, D. T.; Waber, J. T. In International Tables for X-ray Crystallography; Kynoch Press: Birmingham, U.K., 1974; Vol. 4, Table 2.2A.
61. Creagh, D. C.; McAuley, W. J. In International Tables for Crystallography; Wilson, A. J. C., Ed.; Kluwer Academic: Boston, 1992; Vol. C, Table 4.2.6.8, pp 219-222.
62. Creagh, D. C.; Hubbel, J. H. In International Tables for Crystallography; Wilson, A. J. C., Ed.; Kluwer Academic: Boston, 1992; Vol. C., Table 4.2.4.3, pp 200-206.
63. TeXsan Crystal Structure Analysis Package; Molecular Structure Corp., The Woodlands, TX, 1992.