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Volumn 121, Issue 33, 1999, Pages 7606-7617

Modeling the hydrodesulfurization reaction at nickel. Unusual reactivity of dibenzothiophenes relative to thiophene and benzothiophene

Author keywords

[No Author keywords available]

Indexed keywords

DIBENZOTHIOPHENE DERIVATIVE; NICKEL; ORGANOSULFUR DERIVATIVE;

EID: 0033603883     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9905997     Document Type: Article
Times cited : (173)

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    • For examples of related Ni(II)/Ni(I) potentials, see: (a) Kim, J. S.; Reibenspies, J. H.; Darensbourg, M. Y. J. Am. Chem. Soc. 1996, 118, 4115. (b) Morgenstern, D. A.; Ferrence, G. M.; Washington, J.; Henderson, J. J.; Rosenhein, L.; Heise, J. D.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1996, 118, 2198. (c) Osterloh, F.; Saak, W.; Pohl, S. J. Am. Chem. Soc. 1997, 119, 5648.
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    • note
    • The numbering scheme for dibenzothiophene is: matrix presented.
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    • note
    • 1,9-Dimethyldibenzothiophene was an impurity in the preparation of 4-methyldibenzothiophene. See ref 24.
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    • note
    • It has been noted that the integration program SAINT produces cell constant errors that are unreasonably small, since systematic error is not included. More reasonable errors might be estimated at 10x the listed values.
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    • note
    • 2]].


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