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Volumn 119, Issue 24, 1997, Pages 5648-5656

Unidentate and bidentate binding of nickel(II) complexes to an Fe4S4 cluster via bridging thiolates: Synthesis, crystal structures, and electrochemical properties of model compounds for the active sites of nickel containing CO dehydrogenase/acetyl-CoA synthase

Author keywords

[No Author keywords available]

Indexed keywords

ACETYL COENZYME A SYNTHETASE; CARBON MONOXIDE DEHYDROGENASE; METAL COMPLEX; NICKEL; SULFUR DERIVATIVE;

EID: 0030791787     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja970194r     Document Type: Article
Times cited : (62)

References (73)
  • 5
    • 0004183598 scopus 로고
    • Reedijk, J., Ed.; Marcel Dekker: New York
    • (e) Cammack, R. In Bioinorganic Catalysis; Reedijk, J., Ed.; Marcel Dekker: New York, 1993; pp 189-225.
    • (1993) Bioinorganic Catalysis , pp. 189-225
    • Cammack, R.1
  • 22
    • 33749100904 scopus 로고
    • Hillhouse, G. L.; Matsunaga, P. T. Angew. Chem. 1994, 106, 1841; Angew. Chem., Int. Ed. Engl. 1994, 33, 1748.
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 1748
  • 44
    • 1842272645 scopus 로고    scopus 로고
    • note
    • 26
  • 47
    • 0030475068 scopus 로고    scopus 로고
    • C.-H. Lai, J. H. Reibenspies, M. Y. Darensbourg, Angew. Chem. 1996, 108, 2551; Angew. Chem., Int. Ed. Engl. 1996, 35, 2390.
    • (1996) Angew. Chem., Int. Ed. Engl. , vol.35 , pp. 2390
  • 51
    • 0008650201 scopus 로고
    • Saak, W.; Pohl S. Z. Naturforsch. 1985, 40b, 1105. The cluster was obtained as a THF solvate by a modified procedure: Benzyltri-n-butylammonium iodide was used instead of benzyltrimethylammonium iodide, and the reaction mixture, after being refluxed for 12 h, was not taken to dryness in vacuo, but was cooled to room temperature and stored overnight to afford the crystalline product. The crystals were filtered off, washed with THF, and dried in vacuo.
    • (1985) Z. Naturforsch. , vol.40 B , pp. 1105
    • Saak, W.1    Pohl, S.2
  • 53
    • 1842303531 scopus 로고
    • Göttingen, FRG
    • Sheldrick, G. M., Göttingen, FRG, 1990, 1993.
    • (1990) , pp. 1993
    • Sheldrick, G.M.1
  • 54
    • 1842319689 scopus 로고    scopus 로고
    • note
    • 4 cluster was not further developed.
  • 56
    • 0009746605 scopus 로고
    • and literature cited therein
    • Holm, R. H. Adv. Inorg. Chem. 1992, 38, 1 and literature cited therein.
    • (1992) Adv. Inorg. Chem. , vol.38 , pp. 1
    • Holm, R.H.1
  • 58
    • 1842265831 scopus 로고    scopus 로고
    • note
    • 17-19,21,22,25,26 (38) S(5) and S(7) deviate by +6 and +5.4 pm and S(6) and S(8) by -5.4 and -6.0 pm, respectively, from the least-squares plane of these four atoms, whereas S(10,12) are located 13.2 pm above and S(9,11) are located 12.1 pm below the least-squares plane of the Ni-coordinated S atoms.
  • 59
    • 84914356001 scopus 로고
    • and literature cited therein
    • Pohl, S.; Saak, W. Z. Naturforsch. 1988, 43b, 457 and literature cited therein.
    • (1988) Z. Naturforsch. , vol.43 B , pp. 457
    • Pohl, S.1    Saak, W.2
  • 62
    • 0006040256 scopus 로고
    • 4 core exhibits distortions, which are similar to those of 3 and 6. (a) Kanatzidis, M. G.; Coucouvanis, D.; Simopoulos, A.; Kostikas, A.; Papaefthymiou, V. J. Am. Chem. Soc. 1985, 107, 4925. (b) Kanatzidis, M. G.; Ryan, M.; Coucouvanis, D.; Simopoulos, A.; Kostikas, A. Inorg. Chem. 1983, 22, 179.
    • (1983) Inorg. Chem. , vol.22 , pp. 179
    • Kanatzidis, M.G.1    Ryan, M.2    Coucouvanis, D.3    Simopoulos, A.4    Kostikas, A.5
  • 63
    • 1842265830 scopus 로고    scopus 로고
    • note
    • 3 and Cl.
  • 64
    • 1842393147 scopus 로고    scopus 로고
    • note
    • 23
  • 66
    • 0001283785 scopus 로고
    • 4 clusters for which a contact shift mechanism is dominant. See: Weigel, J. A.; Holm, R. H. J. Am. Chem. Soc. 1991, 113, 4184.
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 4184
    • Weigel, J.A.1    Holm, R.H.2
  • 70
    • 1842317796 scopus 로고    scopus 로고
    • 4 clusters usually are one-electron processes. See ref 40
    • 4 clusters usually are one-electron processes. See ref 40.
  • 72
    • 1842304427 scopus 로고    scopus 로고
    • note
    • 3CN.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.