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note
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Z-3-(4-cyanostyryl)pyridine was prepared in 27% yield by a room-temperature Wittig reaction between (4-cyanobenzyl)triphenylphos-phonium bromide and 3-pyridinecarboxaldehyde with NaOH as the base in dichloromethane. The product was purified by silica gel column chromatography [hexane-ethyl acetate (1 : 1)].
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1b Also see: O. R. Evans, Z. Wang, R.-G. Xiong, B. M. Foxman and W. Lin, Inorg. Chem., 1999, 38, 2969.
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0344050386
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note
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Thermogravimetric analyses indicated a 1.7% weight loss in the range 130-240 °C for 1 (1.7% expected for the loss of one half of water molecule per formula unit).
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16
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0344050387
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note
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The solvated water molecule (O9) is ca. 3.5 Å away from both O1 and 03.
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