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Volumn 119, Issue 8, 1997, Pages 1916-1922

Determination of reactive intermediates in iron porphyrin complex-catalyzed oxygenations of hydrocarbons using isotopically labeled water: Mechanistic insights

Author keywords

[No Author keywords available]

Indexed keywords

IRON; PORPHYRIN;

EID: 0030936477     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9629118     Document Type: Article
Times cited : (145)

References (54)
  • 5
    • 0011697055 scopus 로고
    • (e) Meunier, B. Chem. Rev. 1992, 92, 1411-1456.
    • (1992) Chem. Rev. , vol.92 , pp. 1411-1456
    • Meunier, B.1
  • 6
  • 26
    • 1842385195 scopus 로고    scopus 로고
    • note
    • III-MCPBA adduct is stable for more than 2 h in dichloromethane solution at -78°C and is the sole oxidant for olefin epoxidation. See ref 7a.
  • 29
    • 1842310068 scopus 로고    scopus 로고
    • note
    • III-OOH.
  • 44
    • 1842321495 scopus 로고    scopus 로고
    • note
    • 20TPP)Cl and MCPBA. We obtained the same type of a rhombic EPR signal as shown in figure 3 until the reaction temperature reached -10°C, indicating that a significant amount of acylperoxo Fe(III) porphyrin complex was still responsible for the cyclooctene epoxidation at high temperature.
  • 51
    • 0001588705 scopus 로고
    • The observation of no oxygen exchange between the oxo Cr(V) complex of heteropolytungstate and labeled water might be due to the fact that the water molecule cannot bind to the axial position of the chromium oxo complex. Khenkin, A. M.; Hill, C. L. J. Am. Chem. Soc. 1993, 115, 8178-8186.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 8178-8186
    • Khenkin, A.M.1    Hill, C.L.2
  • 52
    • 0001586619 scopus 로고
    • 18O, although the axial position of horseradish peroxidase is coordinated by a histidine residue. The authors suggested that the oxygen exchange takes place at the same site of the oxo group, (a) Hashimoto, S.; Tatsuno, Y.; Kitagawa, T. Proc. Natl. Acad. Sci. U.S.A. 1986, 83, 2417-2421.
    • (1986) Proc. Natl. Acad. Sci. U.S.A. , vol.83 , pp. 2417-2421
    • Hashimoto, S.1    Tatsuno, Y.2    Kitagawa, T.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.