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Volumn 120, Issue 29, 1998, Pages 7328-7336

Molecular recognition on functionalized self-assembled monolayers of alkanethiols on gold

Author keywords

[No Author keywords available]

Indexed keywords

BARBITURIC ACID DERIVATIVE; GOLD; ISOPHTHALIC ACID; THIOL DERIVATIVE;

EID: 0032578196     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973166h     Document Type: Article
Times cited : (129)

References (118)
  • 9
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    • Bard, A. J., Ed.; Marcel Dekker: New York
    • Murray, R. W. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1984, Vol. 13.
    • (1984) Electroanalytical Chemistry , vol.13
    • Murray, R.W.1
  • 18
    • 79959769659 scopus 로고
    • Feast, W. J., Munro, H. S., Eds.; Wiley: Chichester, U.K., Chapter 10
    • (d) Durrani, A. A.; Chapman, D. In Polymer Surfaces and Interfaces; Feast, W. J., Munro, H. S., Eds.; Wiley: Chichester, U.K., 1987; Chapter 10.
    • (1987) Polymer Surfaces and Interfaces
    • Durrani, A.A.1    Chapman, D.2
  • 21
    • 0011885321 scopus 로고
    • Colwell, R. R., Parisen, E. R., Sinskey, A. J., Eds.; Hemisphere: New York
    • (b) Tosteson, T. R. In Biotechnology of Marine Polysaccharides; Colwell, R. R., Parisen, E. R., Sinskey, A. J., Eds.; Hemisphere: New York, 1985; pp 77-115.
    • (1985) Biotechnology of Marine Polysaccharides , pp. 77-115
    • Tosteson, T.R.1
  • 38
    • 3543042073 scopus 로고
    • Proceedings of the International Conference on Langmuir-Blodgett Films, 2nd
    • (f) Proceedings of the International Conference on Langmuir-Blodgett Films, 2nd. Thin Solid Films 1985, 132.
    • (1985) Thin Solid Films , pp. 132
  • 43
  • 98
    • 0001989368 scopus 로고
    • Molecular recognition of barbiturates in context of Langmuir Blodgett films has been investigated. See: (a) Honda, Y.; Kurihara, K.; Kunitake, T. Chem. Lett. 1991, 681.
    • (1991) Chem. Lett. , pp. 681
    • Honda, Y.1    Kurihara, K.2    Kunitake, T.3
  • 102
    • 3543024729 scopus 로고    scopus 로고
    • note
    • 3, the amide protons of the isophthalate appear at 8.40 ppm and the amine protons at 4.36 ppm. In the same solvent, the imide protons of the barbiturate 2a resonate at 7.79 ppm. A stoichiometry-dependent deshielding of all of the indicated signals was observed during the titration. Upon addition of 1 equiv of 2a to a solution of 8 at room temperature, a downfield shift for both sets of protons in 8 is observed, to 9.97 and 5.49 ppm, respectively. However, the imide protons of 2a showed a very broad signal at 12-13 ppm, which was difficult to distinguish from the baseline. Addition of excess of barbiturate 2a did not result in further deshielding of the indicated signals, thus confirming the 1:1 stoichiometry.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.