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In control experiments without Pd catalyst and ligands, phenyl triflate decomposed faster in THF, DMF, andp-dioxane than in toluene under the condition of preformed sodium butanethiolate. The major byproduct was phenol. Thus, toluene was chosen as the solvent in our studies.
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In control experiments without Pd catalyst and ligands, phenyl triflate decomposed faster in THF, DMF, andp-dioxane than in toluene under the condition of preformed sodium butanethiolate. The major byproduct was phenol. Thus, toluene was chosen as the solvent in our studies.
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33847524256
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The mechanism for this reaction presumably follows a similar pathway to the one proposed by Buchwald43 for the palladium-catalyzed animation of aryl Inflates, although no intermediates in the catalytic cycle have yet been identified or isolated.
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The mechanism for this reaction presumably follows a similar pathway to the one proposed by Buchwald43 for the palladium-catalyzed animation of aryl Inflates, although no intermediates in the catalytic cycle have yet been identified or isolated.
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20
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