First palladium-catalyzed aminations of aryl chlorides

Tetrahedron Letters

Volumn 38, Issue 12, 1997, Pages 2073-2074

  Beller, Matthias ^a   Riermeier, Thomas H ^a   Reisinger, Claus Peter ^a   Herrmann, Wolfgang A ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

PALLADIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

AMINATION; ARTICLE; CATALYSIS; CHEMICAL REACTION; DRUG SYNTHESIS;

EID: 0031585038     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)00289-X     Document Type: Article

References (18)

1. 1. Part 2 of the series Palladium-Catalyzed Reactions for Fine Chemical Synthesis; for part 1 see Beller, M.; Eckert, M.; Vollmüller, F.; Bogdanovic, S.; Geißler, H. Angew. Chem. 1997, in press.
2. 1. Part 2 of the series Palladium-Catalyzed Reactions for Fine Chemical Synthesis; for part 1 see Beller, M.; Eckert, M.; Vollmüller, F.; Bogdanovic, S.; Geißler, H. Angew. Chem. 1997, in press.
3. 2. (a) Guram, A. S.; Rennels, R. A.; Buchwald, S. L. Angew. Chem. Int. Ed. Engl. 1995, 34, 1348;
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11. 3. Recently Buchwald reported the amination of 2-chloropyridine, which is an extremly activated heteroaryl chloride, and displays similar reactivity compared to aryl bromides: Wagaw, S.; Buchwald, S. L. J. Org. Chem. 1996, 61, 7240.
12. 4. (a) Herrmann, W. A.; Broßmer, C.; Öfele, K.; Reisinger, C.-P.; Priermeier, T.; Beller, M.; Fischer, H. Angew. Chem. Int. Ed. Engl. 1995, 34, 1844;
13. (b) Beller, M.; Fischer, H.; Herrmann, W. A.; Öfele, K.; Broßmer, C. Angew. Chem. Int. Ed. Engl. 1995, 34, 1848.
14. 5. (a) Heaney, H. Chem. Rev, 1962, 62, 81;
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17. 3, 90.56 MHz) δ (ppm) 24.3, 25.4, 49.3, 114.6, 119.2 (q, J = 32.8 Hz), 126.3 (q, J = 3.6 Hz), 153.8.
18. 7. Louie, J.; Hartwig, J. F. Angew.Chem. Int. Ed. Engl. 1996, 35, 2359.