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Double chain surfactants based on a dialkyl amino group are known. In an AFM study of a Langmuir Blodgett film of one of these, the molecules were believed to be oriented roughly perpendicular to the surface but molecular scale periodicities were not observed (Oishi, Y.; Kato, T.; Kuramori, M.; Suehiro, K.; Ariga, K.; Kamino, A.; Koyano, H.; Kunitake, T. Chem. Lett. 1996, 857-858).
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Straight and bent conformers have been considered previously in a study of alkylated anthroquinoes physisorbed on graphite. In the images shown here, alkyl group spacings are similar to those in the models advanced in this paper (Stabel, A.; Heinz, R.; Rabe, J. P.; Wegner, G.; De Schryer, F. C.; Corens, D.; Dehaen, W.; Süling, C. J. Phys. Chem. 1995, 99, 8690-8697).
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It was also possible to prepare a sample in which both kinds of structures were observed by flame drying only half of the tube
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This argument might be relevant to strained layer epitaxy in Langmuir Blodgett films on mica. In this latter case, the strain is perpendicular to the surface and is relieved upon further layer growth (Viswanathan, R.; Zasadzinski, J. A.; Schwartz, D. K. Science 1993, 261, 449-452).
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