Spectroscopic and electrochemical probes of electronic coupling in some cyanide-bridged transition metal donor/acceptor complexes

Journal of Physical Chemistry A

Volumn 101, Issue 45, 1997, Pages 8441-8459

  Watzky, Murielle A ^a   Macatangay, Ariel V ^a   Van Camp, Richard A ^a   Mazzetto, Selma E ^a   Song, Xiaoqing ^a   Endicott, John F ^a   Buranda, Tione ^a  

^a WAYNE STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARRIER CONCENTRATION; CHARGE TRANSFER; CYANIDES; ELECTRIC CHARGE; ELECTROCHEMISTRY; ELECTRONIC DENSITY OF STATES; MOLECULAR STRUCTURE; RUTHENIUM COMPOUNDS; SOLVENTS; SPECTROSCOPIC ANALYSIS;

ELECTRONIC COUPLING;

COMPLEXATION;

EID: 0031556652     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp971914j     Document Type: Article

References (124)

1. Barbara, P.; Meyer, T. J.; Ratner, M. J. Phys. Chem. 1996, 100, 13148.
2. Mulliken, R. S.; Person, W. B. Molecular Complexes; Wiley-Interscience: New York, 1967.
3. (a) Hush, N. S. Electrochim. Acta 1968, 13, 1005.
4. (b) Hush, N. S. Prog. Inorg. Chem. 1968.
5. Newton, M. D. Chem. Rev. 1991, 91, 767.
6. Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
7. Richardson, D. E.; Taube, H. Coord. Chem. Rev. 1984, 60, 107.
8. Haim, A. Comments Inorg. Chem. 1984, 4, 113.
9. Endicott, J. F. Acc. Chem. Res. 1988, 21, 59.
10. Billing, R.; Rehorick, D.; Hennig, H. Top. Curr. Chem. 1970, 152.
11. Crutchley, R. J. Adv. Inorg. Chem. 1994, 41, 273.
12. Ward, M. D. Chem. Soc. Rev. 1995, 21.
13. Fackler, J. P. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; Wiley: London, 1994; Vol. 5, p 2270.
14. Cannon, R. D. Electron Transfer; Butterworth: London, 1980.
15. Endicott, J. F. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; Wiley; London, 1994.
16. Electron Transfer in Biology and the Solid State; Johnson, M. K.; King, R. B.; Kurtz, Jr., D. M.; Kutal, C.; Morton, M. L.; Scott, R. A., Eds.; ACS Advances in Chemistry Series 226; American Chemical Society: Washington, DC, 1980.
17. Fox, M. A., Channon, M., Eds. Photoinduced Electron Transfer, Elsevier: Amsterdam; 1988, Parts A-D.
18. Newton, M. D.; Sutin, N. Annu. Rev. Phys. Chem. 1988, 35, 437.
19. Weaver, M. J. Chem. Rev. 1992, 92, 463.
20. Wasielewski, M. R. Chem. Rev. 1993, 92, 435.
21. Jordan, K. D.; Padden-Row, M. N. Chem. Rev. 1992, 92, 395.
22. Isied, S. S.; Ogawa, M. Y.; Wishart, J. F. Chem. Rev. 1992, 92, 381.
23. Winkler, R. J.; Gray, H. E. Chem. Rev. 1992, 92, 369.
24. Masuda, A.; Masuda, Y.; Fukuda, Y. J. Phys. Chem. 1997, 101, 2245.
25. Tolbert, L. M.; Zhao, X. J. Am. Chem. Soc. 1997, 117, 3253.
26. Kestner, N.; Logan, J.; Jortner, J. J. Phys. Chem. 1974, 78, 2148.
27. Beratan, D. N.; Onuchic, J. N.; Bens, J. N.; Bowler, B. E.; Gray, H. B. J. Am. Chem. Soc. 1990, 112, 7915.
28. Lopez-Castillo, J.-M.; Jay-Gerin, J.-P. J. Phys. Chem. 1996, 100, 14289.
29. Reimers, J. R.; Hush, N. S. Chem. Phys. 1996, 208, 177.
30. (a) Cave, R. J.; Newton, M. D. Chem. Phvs. Lett. 1996, 249, 15.
31. (b) Cave, R. J.; Newton, M. D.; Kumar, K; Zimmet, M. D. J. Phys. Chem. 1995, 99, 17501.
32. McConell, H. M. J. Chem. Phys. 1961, 35, 508.
33. Kuzentsov, A. M. Charge Transfer in Physics, Chemistry and Biology; Gordon and Breach: Reading, U.K., 1995.
34. (a) Zhang, L.-T.; Ko, J.; Ondrechen, M. J. J. Phys. Chem. 1989, 93, 3030.
35. (b) Ondrechen, M. J.; Gozashiti, S.; Zhang, L.-T.; Zhou, F. In Electron Transfer in Biology and the Solid State; Johnson, M. K., King, R. B., Kurz, D. M., Kutal, C., Norton, M. L., Scott, R. A., Eds.; ACS Advances in Chemistry Series No. 226, American Chemical Society: Washington, DC. 1990; p 225.
36. Ferretti, A.; Lami, A; Ondrechen, M. J.; Villani, G. J. Phys. Chem. 1995, 99, 10484.
37. Peipho, S. B.; Krausz, E. R.; Schatz, P. N. J. Am. Chem. Soc. 1978, 100, 2996.
38. (a) Piepho, S. B. J. Am. Chem. Soc. 1988, 110, 6319.
39. (b) Piepho, S. B. J. Am. Chem. Soc. 1990, 112, 4197.
40. Bixon, M.; Jortner, J.; Verhoeven, J. W. J. Am. Chem. Soc. 1994, 116, 7349.
41. Marcus, R. A. Annu. Rev. Phys. Chem. 1965, 15, 155.
42. Calzado, C. J.; Sanz, J. F.; Costello, O.; Caballo, R. J. Phys. Chem. 1997, 101, 1716.
43. (a) Endicott, J. F.; Song, X.; Watzky, M. A. Chem. Phys. 1993, 176, 427.
44. (b) Endicott, J. F.; Song, X.; Watzky, M. A.; Buranda, T. Photochem. Photobiol. A: Chem. 1994, 92, 181.
45. (c) Endicott, J. F.; Watzky, M. A.; Song, X.; Buranda, T. Coord. Chem. Rev. 1997, 159, 295.
46. (d) Endicott, J. F.; Watzky, M. A.; Macatangay, A. V.; Mazzetto, S. E.; Song, X.; Buranda, T. In Electron and Ion Transport in Condensed Media; Kornyshev, A., Ed.; World Scientific Publishers: Singapore, in press.
47. Watzky, M. A.; Endicott, J. F.; Song, X.; Lei, Y.; Macatangay, A. Inorg. Chem. 1996, 35, 3463.
48. Schwarz, C. L.; Endicott, J. F. Inorg. Chem. 1995, 34, 4572.
49. Marcus, R. A. J. Phys. Chem. 1989, 93, 3078.
50. (a) Endicott, J. F.; Ramasami, T.; Gaswick, D. C.; Tamilarasan, R.; Heeg, M. J.; Brubaker, G. R.; Pyke, S. C. J. Am. Chem. Soc. 1983, 105, 5301.
51. (b) Ramasami, T.; Endicott, J. F. J. Phys. Chem. 1986, 90, 3740.
52. (a) de la Rosa, R.; Chang, P. J.; Salaymeth, F.; Curtis, J. C. Inorg. Chem. 1985, 24, 4229.
53. (b) Salaymeth, F.; Berhaue, S.; Yusof, R.; de la Rosa, R.; Fung, E. Y.; Matamoros, R.; Law, K. W.; Zheng, Q.; Kober, E. M.; Curtis, J. C. Inorg. Chem. 1993, 32, 3895.
54. (a) Mines, G. A.; Roberts, J. A.; Hupp, J. T. Inorg. Chem. 1992, 31, 125.
55. (b) Mines, G. A.; Roberts, J. A.; Bebel, J. C.; Absi, M. P.; Hupp, J. T. J. Am. Chem. Soc. 1992, 114, 7957.
56. (a) Saleh, A. A.; Crutchley, R. J. Inorg. Chem. 1990, 29, 2132.
57. (b) Evans, C. E. B.; Ducharme, D.; Naklicki, M. L.; Crutchley, R. J. Inorg. Chem. 1995, 34, 1350.
58. (a) Gamelin, D. R.; Bominaar, E. L.; Mathonière, C.; Kirk, M. L.; Girerd, J.-J.; Solomon, E. I. Inorg. Chem. 1996, 35, 4323.
59. (b) Gamelin, D. R.; Bominaar, E. L.; Kirk, M. L.; Wieghardt, K.; Solomon, E. I. J. Am. Chem. Soc. 1996, 118, 8085.
60. Creutz, C.; Newton, M. D.; Sutin, N. Photochem. Photobiol. A: Chem. 1994, 82, 47.
61. Shin, Y. K.; Brunschwig, B. S.; Creutz, C.; Sutin, N. J. Phys. Chem. 1996, 100, 8157.
62. Karki, L.; Lu, H. P.; Hupp, J. T. J. Phvs. Chem. 1996, 100, 15637.
63. Reimers, J. R.; Hush, N. S. J. Phys. Chem. 1991, 95, 9773.
64. (a) Oh, D. H.; Boxer, S. G. J. Am. Chem. Soc. 1990, 112, 8161.
65. (b) Oh, D. H.; Sano, M.; Boxer, S. G. J. Am. Chem. Soc. 1991, 113, 6880.
66. 4 = teta = 5,12-meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane.
67. Lessard, R. B.; Heeg, M. J.; Buranda, T.; Perkovic, M. W.; Schwarz, C. L.; Rudong, Y.; Endicott, J. F. Inorg. Chem. 1992, 31, 3091.
68. Kane-Maguire, N. A. P.; Miller, P. K.; Trzupek, L. S. Inorg. Chim. Acta. 1983, 76, L179.
69. Whimp, P. O.; Curtis, N. F. J. Chem. Soc. A 1996, 867, 1821.
70. Curtis, N. F.; Cook, D. F. J. Chem. Soc., Dalton Trans. 1972, 691.
71. Yung, K. Inorg. Synth. 1980, 20, 111.
72. Riccieri, P.; Zinato, E. Inorg. Chem. 1980, 19, 853.
73. Skibsted, L. H.; Ford, P. C. Inorg. Chem. 1983, 22, 2749.
74. (a) Bignozzi, C. A.; Roffia, S.; Scandola, F. J. Am. Chem. Soc. 1985, 107, 1644.
75. (b) Bignozzi, C. A.; Scandola, F. Inorg. Chem. 1984, 23, 1540.
76. (c) Roffia, S.; Paradisi, C.; Bignozzi, C. A. Electroanal. Chem. Interfacial Eletrochem. 1986, 200, 105.
77. (d) Scandola, F.; Bignozzi, C. A. In Supramol. Photochemistry; Balzani, V., Ed.; NATO ASI Series C 214; Reidel: Dordrecht, The Netherlands; 1987; p 121.
78. (e) Scandola, F.; Roffia, S.; Paradisi, C.; Bignozzi, C. A. Inorg. Chem. 1988, 27, 1108.
79. Macatangay, A. V.; Watzky, M. A.; Mazzetto, S. E.; Endicott, J. F. Work in progress.
80. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; Wiley-Interscience: New York, 1980.
81. Watzky, M. A.; Song, X.; Endicott, J F. Inorg. Chim. Acta 1994, 226, 109.
82. Supporting Information.
83. Forlando, P.; Baraldo, L. M.; Olabe, J. A.; Delia Vedova, C. O. Inorg. Chim. Acta 1994, 223, 37.
84. Karki, L.; Hupp, J. T. J. Am. Chem. Soc. 1997, 119, 4070.
85. -1) absorption at 890 nm.
86. (b) Watzky, M. A., Ph.D. Dissertation, Wayne State University, 1994.
87. Vogler, A.; Kunkley, H. Inorg. Chim. Acta 1981, 53, 205.
88. Lever, A. P. B. Inorganic Electronic Spectroscopy, 2nd ed.; Elsevier: New York, 1984.
89. (a) Alexander, J. J.; Gray, H. B. J. Am. Chem. Soc. 1968, 90, 4260.
90. (b) Gray, H. B.; Beach, N. A. J. Am. Chem. Soc. 1963, 85, 2922.
91. (c) Gutterman, D. F.; Gray, H. B. Inorg. Chem. 1972, 11, 1727.
92. (d) Alexander, J. J.; Gray, H. B. Coord. Chem. Rev. 1967, 2, 29.
93. +.
94. McCartney, D. Inorg. Chem. 1991, 30, 3337.
95. Shaw, J.; Everett, G. W. Inorg. Chem. 1985, 24, 1917.
96. Richardson, D. E. Inorg. Chem. 1990, 29, 3213.
97. The stabilization energy of the ground state and destabilization energy of the CT excited state do not enter into eq 2 because the perturbational horizontal displacement of the ground-state PE minimum results in the cancellation of these contributions (we are grateful to Dr. M. D. Newton for bringing this point to our attention).
98. For related arguments see: (a) Lever, A. B. P. Inorg. Chem. 1990, 29, 1271.
99. (b) ibid. 1991, 30, 1980.
100. (c) Masui, H.; Lever, A. B. P. Inorg. Chem. 1993, 32, 2199.
101. 79,80 For simplicity, only one component is considered here. There could also be a weak, high-energy MM'CT component as noted in Figure 5.
102. Zwickel, A. M.; Creutz, C. Inorg. Chem. 1969, 10, 2395.
103. Parker, W. L.; Crosby, G. A. Int. J. Quantum Chem. 1991, 39, 299.
104. -) upon metalation. The absorptivities of these bands are about 4 times larger in the ruthenates than in the parent dicyano complexes.
105. (a) Doorn, S. K.; Stoutland, P. O.; Dyer, R. B.; Woodruff, W. H. J. Am. Chem. Soc. 1992, 114, 3133.
106. (b) Doorn, S. K.; Dyer, R. B.; Stoutland, P. O.; Woodruff, W. H. J. Am. Chem. Soc. 1993, 115, 6398.
107. (a) Walker, G. L.; Barbara, P. F.; Doorn, S. K.; Hupp, J. T. J. Phys. Chem. 1991, 95, 5712.
108. (b) Tominaggi, K; Kliner, D. A. V.; Johnosn, A. E.; Levinger, N. E.; Barbara, P. F. J. Phys. Chem. 1995, 99, 2609.
109. Buranda, T.; Lei, Y.; Endicott, J. F. J. Am. Chem. Soc. 1992, 114, 135.
110. Ponce, A.; Bachrach, M.; Farmer, P. J.; Winkler, J. R. Inorg. Chim. Acta 1996, 243, 135.
111. Endicott, J. F.; Lessard, R. B.; Lei, Y.; Ryu, C. K. In Photoinduced Charge Separation and Energy Migration in Supramolecular Species; Balzani, V., Ed.; NATO ASI C-series; Reidel: Dordrecht, 1987.
112. Nakamoto, K. Infrared and Roman Spectra of Inorganic and Coordination Compounds, 4th ed.; Wiley: New York, 1986.
113. For simplicity we label the electronic states by the center at which the charge is predominantly localized.
114. Reimers, J. R.; Hush, N. S. Photochem. Photobiol. A: Chem. 1994, 82, 31.
115. Bersuker, I. B. The John-Teller Effect and Vibronic Interactions in Modem Chemistry, Plenum: New York, 1984.
116. Fischer, G. Vibronic Coupling; Academic: New York; 1984.
117. Ballhausen, C. J. In Vibronic Processes in Inorganic Chemistry; Flint, C. D., Ed.; Kluwer Academic Publishers: Dordrecht, 1989; p 53.
118. 1/2(obsd) and hDA. For theoretical definitions of the distance parameters see refs 2, 28, 29, and 49.
119. DA = 5.2 Å.
120. 3+ complex. Owing to the uncertainty of this "correction", we have not included this point in Figure 10b.
121. Richardson, D. E.; Sharpe, P. Inorg. Chem. 1993, 32, 1809.
122. 98 that the orthogonality relations would be rigorously applicable.
123. See footnote 41 of Lessard, R. B.; Heeg, M. J.; Buranda, T.; Perkovic, M. W.; Schwarz, C. L.; Rudong, Y.; Endicott, J. F. Inorg. Chem. 1992, 31, 3091.
124. Marcus, R. A. J. Phys. Chem. 1989, 93, 3078.