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Volumn 101, Issue 12, 1997, Pages 2245-2253

First evaluation of ultrafast (ground state) intramolecular electron transfer rate in solution by NMR spin-lattice relaxation. An application to mixed-valence biferrocene monocation (Fe(II), Fe(III))

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Indexed keywords


EID: 0001411788     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp963317n     Document Type: Review
Times cited : (11)

References (93)
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    • The effect of the diffusion process and the distribution between the donor and acceptor at their close distance is another important subject for intermolecular ET studies. (See for example: (a) Rice, S. A. Diffusive-Limited Reactions; Comprehensive Chemical Kinetics Vol. 25; Elsevier: Amsterdam, 1985. (b) Tachiya, M. J. Phys. Chem. 1993, 97, 5911. (c) J. Phys. Chen. 1989, 93, 7050. (d) Sumi, H. J. Phys. Chem. 1991, 95, 3334.)
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    • The effect of the diffusion process and the distribution between the donor and acceptor at their close distance is another important subject for intermolecular ET studies. (See for example: (a) Rice, S. A. Diffusive-Limited Reactions; Comprehensive Chemical Kinetics Vol. 25; Elsevier: Amsterdam, 1985. (b) Tachiya, M. J. Phys. Chem. 1993, 97, 5911. (c) J. Phys. Chen. 1989, 93, 7050. (d) Sumi, H. J. Phys. Chem. 1991, 95, 3334.)
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    • The effect of the diffusion process and the distribution between the donor and acceptor at their close distance is another important subject for intermolecular ET studies. (See for example: (a) Rice, S. A. Diffusive-Limited Reactions; Comprehensive Chemical Kinetics Vol. 25; Elsevier: Amsterdam, 1985. (b) Tachiya, M. J. Phys. Chem. 1993, 97, 5911. (c) J. Phys. Chen. 1989, 93, 7050. (d) Sumi, H. J. Phys. Chem. 1991, 95, 3334.)
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    • The effect of the diffusion process and the distribution between the donor and acceptor at their close distance is another important subject for intermolecular ET studies. (See for example: (a) Rice, S. A. Diffusive-Limited Reactions; Comprehensive Chemical Kinetics Vol. 25; Elsevier: Amsterdam, 1985. (b) Tachiya, M. J. Phys. Chem. 1993, 97, 5911. (c) J. Phys. Chen. 1989, 93, 7050. (d) Sumi, H. J. Phys. Chem. 1991, 95, 3334.)
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    • - were prepared according to ref 18e with minor modifications
    • - were prepared according to ref 18e with minor modifications.
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    • note
    • hyp.
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    • r(eff) values of the cyclopentadienyl and the fulvalene protons.
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    • note
    • r values in the solvents other than acetone are listed in Table 3.
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    • op were disregarded.
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    • Scrupulous calculations of the v., values according to ref 38b considering the contribution of nonadiababicity gave similar results.
    • Scrupulous calculations of the v., values according to ref 38b considering the contribution of nonadiababicity gave similar results.
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    • note
    • The quantization axis for the dipolar interaction was assumed to be along the main axis of the g tensor because the rotational correlation time is significantly longer than the electron spin relaxation time. (See section 3.2 and Table 1.) The isotropic hyperfine interactions were also assumed.
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    • note
    • + and bfc. (See Table 1.)


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