메뉴 건너뛰기




Volumn 35, Issue 12, 1996, Pages 3463-3473

Red-Shifted Cyanide Stretching Frequencies in Cyanide-Bridged Transition Metal Donor - Acceptor Complexes. Support for Vibronic Coupling

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001422001     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950834w     Document Type: Article
Times cited : (63)

References (68)
  • 7
  • 8
    • 85087582601 scopus 로고    scopus 로고
    • note
    • 8 assume that the electron jumps between reactant and product configurations only after the nuclei have rearranged.
  • 18
    • 2542582774 scopus 로고
    • Ph.D. Dissertation, Wayne State University, Detroit, MI
    • (a) Watzky, M. A., Ph.D. Dissertation, Wayne State University, Detroit, MI, 1994.
    • (1994)
    • Watzky, M.A.1
  • 32
    • 85087581496 scopus 로고    scopus 로고
    • note
    • 4 = 5,12-rac-5,7,7,12,14,14-hexamethyl-l,4,8,11-tetraazacyclotelradecane.
  • 41
    • 85087582895 scopus 로고    scopus 로고
    • note
    • 13a
  • 43
    • 2542546211 scopus 로고
    • Ph.D. Dissertation, Wayne State University, Detroit, MI
    • Lei, Y. Ph.D. Dissertation, Wayne State University, Detroit, MI, 1989.
    • (1989)
    • Lei, Y.1
  • 48
    • 2542557082 scopus 로고    scopus 로고
    • note
    • s in all of the complexes, even when other effects are not important.
  • 50
    • 85087580545 scopus 로고    scopus 로고
    • note
    • CN that can be easily attributed to different masses of the coordinated metals. We simply treat this effect as interelectronic repulsion in the MO argument.
  • 51
    • 2542585822 scopus 로고
    • Ph.D. Dissertation, Wayne State University, Detroit, MI
    • Waknine, D. Ph.D. Dissertation, Wayne State University, Detroit, MI. 1994.
    • (1994)
    • Waknine, D.1
  • 59
    • 0542430088 scopus 로고
    • Saunders: Philadelphia
    • Drago, R. S. Physical Methods; Saunders: Philadelphia, 1992; p 187.
    • (1992) Physical Methods , pp. 187
    • Drago, R.S.1
  • 67
    • 2542569135 scopus 로고    scopus 로고
    • note
    • This assumption is consistent with the usual Born-Oppenheimer approximation that electronic relaxation is rapid on the time scale for nuclear motion. However, this is in contrast to a fundamental assumption of most nonadiabatic electron transfer theories: that the electron "jumps" only after nuclear rearrangement has taken place. The latter is equivalent to the CBOA mentioned in the Introduction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.