Selectivity in ring-opening metatheses

Tetrahedron

Volumn 53, Issue 48, 1997, Pages 16511-16520

  Tallarico, John A ^a   Randall, Michele L ^a   Snapper, Marc L ^a  

^a BOSTON COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; ALKENE DERIVATIVE; CYCLOBUTANE DERIVATIVE;

COMPLEX FORMATION; CONFERENCE PAPER; PRIORITY JOURNAL; STEREOCHEMISTRY; STOICHIOMETRY; SYNTHESIS;

EID: 0030785438     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)01032-6     Document Type: Conference Paper

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48. Isotope labeling experiments suggest that the degenerate metathesis of the terminal olefin is not occurring at low conversion of starting materials in our cross-metathesis.
49. This is not what is observed in the cross-metathesis of 1a with various terminal olefins (see ref. 1d).
50. The conformation of the disubstituted alkylidene illustrated in Table 2 is presented such that interactions with other substituents on ruthenium are minimized.
51. Estimated from the observed ROM olefin stereoselectivity in the formation of 26.
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