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5
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0000011726
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Syntheses
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Isolation: (a) Ayanoglu, E.; Gebreyesus, T.; Beechan, C. M.; Djerassi, C. Tetrahedron 1979,35,1035-1039. Syntheses:
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0001077422
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For the preparation of the molybdenum carbene 5, see: Schrock, R. R.; Murdzek, J. S.; Bazan, G. C.; Robbins, J.; DiMare, M.; O'Regan, M. J. Am. Chem. Soc. 1990, 112, 3875-3886.
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33847484511
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For the formation of medium-sized rings by RCM see
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For the formation of medium-sized rings by RCM see:
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22
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0001647405
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(a) Miller, S. J.; Kim, S.-H.; Chen, Z.-R.; Grubbs, R. H. J. Am. Chem. Soc. 1995, 117, 2108-2109.
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0029870160
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Martin, S. F.; Chen, H.-J.; Courtney, A. K.; Liao, Y.; Pätzel, M.; Ramser, M. N.; Wagman, A. S. Tetrahedron 1996, 52, 7251-7264.
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(e) Martin, S. F.; Liao, Y.; Wong, Y.; Rein, T. Tetrahedron Lett. 1994, 691-694.
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Martin, S.F.1
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(f) Visser, M. S.; Heron, N. M.; Didiuk, M. T.; Sagal, J. F.; Hoveyda, A. H. J. Am. Chem. Soc. 1996, 118, 4291-4298.
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Hoveyda, A.H.5
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31
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33847463535
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For pertinent reviews, see
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For pertinent reviews, see:
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34
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0020261159
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Suzuki, M.; Kawagishi, T.; Suzuki, T.; Noyori, R. Tetrahedron Lett. 1982, 4057-4060.
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Suzuki, M.1
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36
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0003435733
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The Ca-atoms of substituents in frans-disubstituted cyclopentanes resonate at significantly lower field than that in the corresponding cis-disubstituted ones, cf.: Thieme: Stuttgart
-
13C-NMR Spektroskopie; Thieme: Stuttgart, 1984.
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13C-NMR Spektroskopie
-
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Kalinowski, H.-O.1
Berger, S.2
Braun, S.3
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40
-
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0000044737
-
-
however, the conversion was low and the products formed were difficult to separate from the unreacted starting material
-
4 (11a:12a = 2.3:1), cf.: Reetz, M. T.; Westermann, J.; Steinbach, R.; Wenderoth, B.; Peter, R.; Ostarek, R.; Maus, S. Chem. Ber. 1985, 118, 1421-1440; however, the conversion was low and the products formed were difficult to separate from the unreacted starting material.
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Reetz, M.T.1
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Peter, R.5
Ostarek, R.6
Maus, S.7
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41
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37049077957
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(a) For the preparation of Mg-graphite and applications in pinacol coupling reactions, see: Fürstner, A.; Csuk, R.; Rohrer, C.; Weidmann, H. J. Chem. Soc., Perkin Trans. 1 1988, 1729-1734.
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(b) Reviews on activated metal systems: Fürstner, A. Angew. Chem. 1993, 705, 171-197;
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Fürstner, A.1
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45
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84949413212
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Müller, E., Ed.; Thieme: Stuttgart
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2 in THF was prepared from Mg and dichloroethane according to: Nützel, K. in Houben-Weyl, Methoden der Organischen Chemie; Müller, E., Ed.; Thieme: Stuttgart, 1973; Vol. XIII/2a, p 176.
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Houben-Weyl, Methoden Der Organischen Chemie
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Nützel, K.1
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47
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33847476555
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For details see the Supporting Information.
-
For details see the Supporting Information.
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