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note
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Although these values do not represent actual binding energies for Al-C, Ga-C, and As-C on the epilayer surface during MOCVD growth, the relationship among them can be regarded as the binding energy between C and metals. Since the binding energy of As-C is smaller than that of Al-C and Ga-C, C atoms always preferably occupy As sites in GaAs and AlGaAs systems. The conduction type of C-doped AlGaAs, therefore, remains p type over the whole As mole fraction range, in contrast to the amphoteric nature of the C dopant in InGaAs (Ref. 11).
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