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Volumn 35, Issue 17, 1996, Pages 5027-5031

Trans or (Unusual) Cis Geometry in d2 Octahedral Dioxo Complexes. A DFT Study

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EID: 0001135451     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951523o     Document Type: Article
Times cited : (16)

References (48)
  • 7
    • 0000745806 scopus 로고
    • 0 dioxo complexes, see: (a) Brower, D. C.; Templeton, J. L.; Mingos, D. M. P. J. Am. Chem. Soc. 1987, 109, 5203. (b) Tatsumi, K.; Hoffmann, R. Inorg. Chem. 1980, 19, 2656.
    • (1980) Inorg. Chem. , vol.19 , pp. 2656
    • Tatsumi, K.1    Hoffmann, R.2
  • 8
    • 33845281614 scopus 로고
    • For experimental reviews, see: (a) Holm, R. H. Chem. Rev. 1987, 87, 1401. (b) Holm, R. H.; Donahue, J. P. Polyhedron 1993, 12, 571.
    • (1987) Chem. Rev. , vol.87 , pp. 1401
    • Holm, R.H.1
  • 9
    • 33845281614 scopus 로고
    • For experimental reviews, see: (a) Holm, R. H. Chem. Rev. 1987, 87, 1401. (b) Holm, R. H.; Donahue, J. P. Polyhedron 1993, 12, 571.
    • (1993) Polyhedron , vol.12 , pp. 571
  • 44
    • 85087231019 scopus 로고    scopus 로고
    • 4a (X-ray structure still unknown)
    • 4a (X-ray structure still unknown).
  • 45
    • 85087231949 scopus 로고    scopus 로고
    • -1 for 11c (dia), 11t (dia), and 11c (para), respectively
    • -1 for 11c (dia), 11t (dia), and 11c (para), respectively.
  • 46
    • 85087229891 scopus 로고    scopus 로고
    • note
    • 13b have shown that, due to the values of the M-O bond lengths (about 0.2 Å longer than in 5). the d-π interactions are almost negligible. DFT calculations on this complex are in progress.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.