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Volumn 2, Issue 10, 1996, Pages 1221-1229

Permethyltitanocene derivatives with naked chalcogen ligands: Synthesis of [(Cp2*Ti)2(μ-E)] and [Cp 2*Ti(η2-E2)] and the role of the terminal chalcogenides [Cp2*Ti(E)] in their interconversion (E = Se, Te)

Author keywords

Chalcogen compounds; Metallocenes; Selenium compounds; Tellarium compounds; Titanium complexes

Indexed keywords

CHALCOGENS; DIMERIC STRUCTURE; DINUCLEAR COMPOUNDS; ELEMENTAL SELENIUM; MULTINUCLEAR NMR SPECTROSCOPY; TELLARIUM COMPOUNDS; TITANIUM COMPLEXES; X RAY STRUCTURAL ANALYSIS;

EID: 0000596575     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.19960021007     Document Type: Article
Times cited : (21)

References (81)
  • 22
    • 84891304984 scopus 로고    scopus 로고
    • note
    • Owing to the poor solubility of 1 in hydrocarbon solvents, measurement of the magnetic moment in solution by the Evans method was not possible.
  • 27
    • 84891325688 scopus 로고    scopus 로고
    • This value was computed by ECP methods: personal communication
    • This value was computed by ECP methods: T. R. Cundari, personal communication.
    • Cundari, T.R.1
  • 28
    • 1542576746 scopus 로고
    • E = Te: E = Se: see ref. [4a]
    • E = Te: D. Fenske, A. Grissinger, Z. Naturforsch. 1990, 45b, 1309. E = Se: see ref. [4a].
    • (1990) Z. Naturforsch. , vol.45 B , pp. 1309
    • Fenske, D.1    Grissinger, A.2
  • 36
    • 84891330687 scopus 로고    scopus 로고
    • see ref. [6]
    • f) see ref. [6].
  • 40
    • 84891303353 scopus 로고    scopus 로고
    • see ref. [6]
    • d) see ref. [6].
  • 45
    • 84891288779 scopus 로고    scopus 로고
    • note
    • The effect of phosphine basicity on the selectivity of desulfurization reactions of titanocene polysulfides has been noted (see ref. [4b]).
  • 47
    • 84891312184 scopus 로고    scopus 로고
    • note
    • 2*Ti=Se(py)].
  • 57
    • 0001721865 scopus 로고
    • 2(μ-Se) has been isolated: No mention of the decomposition of this compound to a paramagnetic species (i.e, 1a) appeared in this report
    • 2] has been isolated: F. Bottomley, T.-T. Chin, G. O. Egharevba, L. M. Kane, D. A. Pataki, P. S. White, Organometallics 1988, 7, 1214. No mention of the decomposition of this compound to a paramagnetic species (i.e, 1a) appeared in this report.
    • (1988) Organometallics , vol.7 , pp. 1214
    • Bottomley, F.1    Chin, T.-T.2    Egharevba, G.O.3    Kane, L.M.4    Pataki, D.A.5    White, P.S.6
  • 58
    • 84891318309 scopus 로고
    • Experimental Organometallic Chemistry (Eds.: A. L. Wayda, M. Y. Darensbourg), American Chemical Society, Washington, DC
    • B. J. Burger, J. E. Bercaw, in Experimental Organometallic Chemistry (Eds.: A. L. Wayda, M. Y. Darensbourg), ACS Symp. Ser. 357; American Chemical Society, Washington, DC, 1987.
    • (1987) ACS Symp. Ser. , vol.357
    • Burger, B.J.1    Bercaw, J.E.2
  • 73
    • 0003990093 scopus 로고
    • Internal report, Department of Theoretical Chemistry, Free University, Amsterdam
    • J. Krijn, E. J. Baerends, Fit Functions in the HFS Method, Internal report, Department of Theoretical Chemistry, Free University, Amsterdam, 1984.
    • (1984) Fit Functions in the HFS Method
    • Krijn, J.1    Baerends, E.J.2
  • 78
    • 84891334788 scopus 로고    scopus 로고
    • note
    • Crystallography data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-1220-23. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: Int. code + (1223) 336-033; e-mail: teched@chemcrys.cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.