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Volumn 21, Issue 17, 2002, Pages 3596-3604

Chelated iridium(III) bis-carbene complexes as air-stable catalysts for transfer hydrogenation

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Indexed keywords

LIGANDS;

EID: 0000845282     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020338x     Document Type: Article
Times cited : (331)

References (66)
  • 5
    • 0037990680 scopus 로고    scopus 로고
    • Personal communication
    • (e) Arduengo, A. J., III. Personal communication.
    • Arduengo A.J. III1
  • 26
  • 51
    • 0000228943 scopus 로고
    • A similar approach combined with considerably more laborious analytical techniques (combustion instead of NMR) has been used to investigate the mechanism of the MPV reduction: Williams, E. D.; Krieger, K. A.; Day, A. R. J. Am. Chem. Soc. 1953, 75, 2404.
    • (1953) J. Am. Chem. Soc. , vol.75 , pp. 2404
    • Williams, E.D.1    Krieger, K.A.2    Day, A.R.3
  • 53
    • 0037652881 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum recorded after 10 min at 70 °C shows a resonance at -17.4 ppm, which disappears within 30 min. Unfortunately, any attempts to stabilize this hydrid species for detailed analysis were unsuccessful.
  • 54
    • 0009712385 scopus 로고
    • However, Hammett correlation has been observed in MPV reduction, see: (a) Pickart, D. E.; Hancock, C. K. J. Am. Chem. Soc. 1955, 77, 4642.
    • (1955) J. Am. Chem. Soc. , vol.77 , pp. 4642
    • Pickart, D.E.1    Hancock, C.K.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.