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Volumn 19, Issue 10, 2000, Pages 2022-2030

Thermolysis reactions of cis-PtR(SiPh3)(PMe2Ph)2 in solution

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EID: 0000796822     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000012t     Document Type: Article
Times cited : (31)

References (46)
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    • note
    • 0 - [2] - [5].
  • 27
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    • (b) For precedents of platinum silylene complexes, see: Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524; J. Am. Chem. Soc. 1998, 120, 7635.
    • (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 2524
    • Mitchell, G.P.1    Tilley, T.D.2
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    • (b) For precedents of platinum silylene complexes, see: Mitchell, G. P.; Tilley, T. D. Angew. Chem., Int. Ed. 1998, 37, 2524; J. Am. Chem. Soc. 1998, 120, 7635.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 7635
  • 30
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    • (c) The C-Si bond formation via α-migration of an alkyl ligand to a silylene ligand has been proposed: Okazaki, M.; Tobita, H.; Ogino, H. J. Chem. Soc., Dalton Trans. 1997, 3531. Ozawa, F.; Kitaguchi, M.; Katayama, H. Chem. Lett. 1999, 1289.
    • (1997) J. Chem. Soc., Dalton Trans. , pp. 3531
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    • (c) The C-Si bond formation via α-migration of an alkyl ligand to a silylene ligand has been proposed: Okazaki, M.; Tobita, H.; Ogino, H. J. Chem. Soc., Dalton Trans. 1997, 3531. Ozawa, F.; Kitaguchi, M.; Katayama, H. Chem. Lett. 1999, 1289.
    • (1999) Chem. Lett. , pp. 1289
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    • and references therein
    • (d) For further information on the related chemistry, see: Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871, and references therein.
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    • The reactivity toward C-C reductive elimination generally increases as the σ-donating ability of the alkyl ligand increases. (a) Tatsumi, K.; Hoffmann, R.; Yamamoto, A.; Stille, J. K. Bull. Chem. Soc. 1981, 54, 1857. (b) Yamamoto, A. Organotransition Metal Chemistry, Fundamental Concepts and Applications; Wiley-Interscience: New York, 1986; p 286. (c) Brown, J. M.; Cooley, N. A. Chem. Rev. 1988, 88, 1031.
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    • The reactivity toward C-C reductive elimination generally increases as the σ-donating ability of the alkyl ligand increases. (a) Tatsumi, K.; Hoffmann, R.; Yamamoto, A.; Stille, J. K. Bull. Chem. Soc. 1981, 54, 1857. (b) Yamamoto, A. Organotransition Metal Chemistry, Fundamental Concepts and Applications; Wiley-Interscience: New York, 1986; p 286. (c) Brown, J. M.; Cooley, N. A. Chem. Rev. 1988, 88, 1031.
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    • The reactivity toward C-C reductive elimination generally increases as the σ-donating ability of the alkyl ligand increases. (a) Tatsumi, K.; Hoffmann, R.; Yamamoto, A.; Stille, J. K. Bull. Chem. Soc. 1981, 54, 1857. (b) Yamamoto, A. Organotransition Metal Chemistry, Fundamental Concepts and Applications; Wiley-Interscience: New York, 1986; p 286. (c) Brown, J. M.; Cooley, N. A. Chem. Rev. 1988, 88, 1031.
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    • note
    • 6.


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