Reactions of alkenylruthenium(II) complexes with hydrosilane: C-Si vs C-H bond formation

Chemistry Letters

Volumn , Issue 9, 1998, Pages 905-906

  Maruyama, Yooichiroh ^a   Yamamura, Kunihiro ^a   Ozawa, Fumiyuki ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032336136     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.905     Document Type: Article

References (20)

1. T. D. Tilley, in "The Chemistry of Organic Silicon Compounds," ed by S. Patai and Z. Rappoport, John Wiley, Chichester, U. K. (1989), p. 1415; P. Brunstein and M. Knorr, J. Organomet. Chem., 500, 21 (1995).
2. T. D. Tilley, in "The Chemistry of Organic Silicon Compounds," ed by S. Patai and Z. Rappoport, John Wiley, Chichester, U. K. (1989), p. 1415; P. Brunstein and M. Knorr, J. Organomet. Chem., 500, 21 (1995).
3. Y. Maruyama, K. Yamamura, I. Nakayama, K. Yoshiuchi, and F. Ozawa, J. Am. Chem. Soc., 120, 1421 (1998).
4. M. R. Torres, A. Vegas, and A. Santos, J. Organomet. Chem., 309, 169 (1986); M. R. Torres, A. Vegas, A. Santos, and J. Ros, J. Organomet. Chem., 326, 413 (1987).
5. M. R. Torres, A. Vegas, and A. Santos, J. Organomet. Chem., 309, 169 (1986); M. R. Torres, A. Vegas, A. Santos, and J. Ros, J. Organomet. Chem., 326, 413 (1987).
6. 3 due to decomposition. The product ratios for such systems (e.g. entries 2 and 3 in Table 1) are based on the ratio of 4/5.
7. 3.
8. -3.
9. 3 (10-30 mM).
10. No sign of the formation of 6 was detected by NMR spectroscopy, consistent with our proposal with the rate-determining formation of 6.
11. 2Ph (M) are as follows: 0.543(8) (0.101), 1.09(2) (0.182), 1.09(2) (0.200), 1.00(2) (0.294).
12. Y. Wakatsuki, H. Yamazaki, Y. Maruyama, and I. Shimizu, J. Organomet. Chem., 430, C60 (1992).
13. 3 ligand, respectively.
14. M. Aizenbergand and D. Milstein, J. Am. Chem. Soc., 117, 6456 (1995).
15. B. A. Arndtsen, R. G. Bergman, T. A. Mobley, and T. H. Peterson, Acc. Chem. Res., 28, 154 (1995); R. H. Crabtree, Chem. Rev., 95, 987 (1995).
16. B. A. Arndtsen, R. G. Bergman, T. A. Mobley, and T. H. Peterson, Acc. Chem. Res., 28, 154 (1995); R. H. Crabtree, Chem. Rev., 95, 987 (1995).
17. L. Abis, A. Sen, and J. Halpern, J. Am. Chem. Soc., 100, 2915 (1978); R. A. Michelin, S. Faglia, and P. Uguagliati, Inorg. Chem., 22, 1831 (1983);
18. L. Abis, A. Sen, and J. Halpern, J. Am. Chem. Soc., 100, 2915 (1978); R. A. Michelin, S. Faglia, and P. Uguagliati, Inorg. Chem., 22, 1831 (1983);
19. S. J. Okrasinski and J. R. Norton, J. Am. Chem. Soc., 99, 295 (1977).
20. A. Milet, A. Dedieu, G. Kapteijn, and G. van Koten, Inorg. Chem., 36, 3223 (1997), and references cited therein.