Conversion of a diruthenium μ-methylene complex, Cp2Ru2(μ-CH2)(μ-CO)(CO)2, into methane through reduction with hydrosilane: Reactivity of silyl-μ-methylene intermediates Cp2Ru2(μ-CH2)(SiR3)(X)(CO) 2 (X = H, SiR3)

Organometallics

Volumn 15, Issue 20, 1996, Pages 4162-4177

  Akita, Munetaka ^a   Hua, Ruimao ^a   Oku, Tomoharu ^a   Tanaka, Masako ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001744853     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960258r     Document Type: Article

References (78)

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54. 3
55. 2-structure like 7 is not possible. But, in this case, too, a definite conclusion cannot be obtained on the basis of the results obtained so far.
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57. 3Si-group migration instead of the H migration shown in Scheme 8.
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63. 4: Hua, R.; Akita, M.; Moro-oka, Y. Unpublished result.
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