Intermediate complexes in the octacarbonyl dicobalt-initiated living polymerization of 3-methyl-1,2-butadiene

Journal of the American Chemical Society

Volumn 118, Issue 40, 1996, Pages 9589-9596

  Sóvágó, Judit ^a   Newton, M Gary ^b   Mushina, Evgenia A ^c   Ungváry, Ferenc ^d  

^a INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^b UNIVERSITY OF GEORGIA   (United States)

^c TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS   (Russian Federation)

^d UNIVERSITY OF PANNONIA   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERIZATION; COBALT COMPOUNDS; MOLECULAR STRUCTURE; ORGANOMETALLICS; POLYMERIZATION; X RAY DIFFRACTION ANALYSIS;

INTERMEDIATE COMPLEXES; METHYLBUTADIENES; OCTACARBONYL DICOBALT;

BUTADIENE;

POLYENE;

ARTICLE; DRUG SYNTHESIS; INFRARED SPECTROPHOTOMETRY; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; TECHNIQUE;

EID: 0030577122     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9542404     Document Type: Article

References (44)

1. Greenfield, H.; Wender, I.; Wotiz, J. H. J. Org. Chem. 1956, 21, 875-878.
2. Nakamura, A. Bull. Chem. Soc. Jpn. 1966, 39, 543-547.
3. (a) Otsuka, S.; Mori, K.; Suminoe, T.; Imaizumi, F. Eur. Polym. J. 1967, 3, 73-83.
4. (b) Gmelins Handbuch der anorganischen Chemie. Ergänzungswerk zur 8.Auflage, Band 5. Kobaltorganische Verbindungen Teil 2; Slawisch, A., Ed.; Verlag Chemie: Weinheim/Bergstr., 1972; pp 112-113.
5. (c) Bowden, F. L.; Giles, R. Caord. Chem. Rev. 1976, 20, 81-106.
6. (d) Kemmitt, R. D. W.; Russel, D. R. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, U.K., 1982; Vol. 5, p 219.
7. (a) Jolly, P. W.; Mynott, R. Adv. Organomet. Chem. 1981, 19, 279-304.
8. (b) Cann, K.; Riley, P. E.; Davis, R. E.; Pettit, R. Inorg. Chem. 1978, 17, 1421-1428.
9. (a) IUPAC Solubility data series Vol. 43. Carbon Monoxide; Cargill, R. W., Ed.; Pergamon Press: Oxford, U.K., 1990; pp 79-81.
10. (b) Gjaldbaek, J. C. Acta Chem. Scand. 1952, 6, 623-633.
11. (c) Unsváry, F. J. Organomet. Chem. 1972, 36, 363-370.
12. (d) Bor, G.; Dietler, U. K.; Pino, P; Poë, A. J. Organomet. Chem. 1978, 154, 301-315.
13. (e) Koelliker, R.; Thies, H. J. Chem. Eng. Data 1993, 38, 437-440.
14. (f) Garland, M.; Horváth, I. T.; Bor, G.; Pino. P. Organometallics 1991, 10, 559-567.
15. 13CO (refs 8d,e).
16. (a) Keller, H. J.; Wawersik, H. Z. Naturforscher. 1965, 20b, 938-942.
17. (b) Bor, G.; Spindler, U. K. International Conference on Organometallic Chemistry, 9th; Sept. 3-7, 1979, Dijon, France, Abstract B56.
18. (c) Klingler, R. J.; Rathke, J. W. J. Am. Chem. Soc. 1994, 116, 4772-4785.
19. (a) Basolo, F.; Wojcicki, A. J. Am. Chem. Soc. 1961, 83, 520-528.
20. (b) Breitschaft, S.; Basolo, F. J. Am. Chem. Soc. 1966, 88, 2702-2706.
21. (c) Roe, D. C. Organometallics 1987, 6, 942-946.
22. (d) Absi-Halabi, M.; Atwood, J. D.; Forbus, N. P.; Brown, T. L. J. Am. Chem. Soc. 1980, 102, 6248-6254.
23. (e) Hoff, C. D.; Ungváry, F.; King, R. B.; Markó, L. J. Am. Chem. Soc. 1985, 107, 666-671.
24. TEMPO = 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical.
25. Jaitner, P.; Huber, W.; Gieren, A.; Betz, H. J. Organomet. Chem. 1986, 311, 379-385.
26. Galvinoxyl = 2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)- p-tolyloxy, free radical.
27. (a) Ellgen, P. Inorg. Chem. 1972, 11, 691-695.
28. (b) Ungváry, F.; Markó, L. Chem. Der. 1972, 105, 2457-2461.
29. Unaváry, F.; Shanshool, J; Markó, L. J. Organomet. Chem. 1985, 296, 155-159.
30. Otsuka, S.; Nakamura, A. Inorg. Chem. 1972, 11, 644-645.
31. Heck, R. F. J. Am. Chem. Soc. 1963, 85, 651-654.
32. -1.
33. Heck, R. F. J. Am. Chem. Soc. 1963, 85, 655-657.
34. Bor, G. Collect. Pap. Symp. Coord. Chem. Tihany 1964, 397-417.
35. Szabó, P.; Markó, L.; Bor, G. Chem. Tech. (Leipzig) 1961, 13, 549-550.
36. Shriver, D. F.; Drezdzon, M. A. The manipulation of Air-Sensitive compounds; Wiley: Malabar, FL, 1986.
37. Prepared from ketene and hydridotetracarbonylcobalt according to ref 22.
38. Ungváry, F. J. Organomet. Chem. 1986, 303, 251-255.
39. Prepared from allyl bromide and sodium tetracarbonylcobaltate according to refs 17 and 24.
40. Heck, R. F.; Breslow, D. S. J. Am. Chem. Soc. 1961, 83, 1097-1102.
41. North, A. C. T.; Phillips, D. C.; Mathews, F. S. Acta Crystallogr. A 1968, A24, 351-359.
42. TEXSAN, Crystal Structure Analysis Package; Molecular Structure Corporation, 1985 and 1992.
43. Altomare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Burla, M. C.; Polidori, G.; Camalli, M. J. Appl. Crystallogr. 1994, 27, 435.
44. Johnson, C. K. ORTEPII. Report ORNL-5138. Oak Ridge National Laboratory, TN, 1976.