The nature of the monomer insertion step in the allylnickel(II)-catalyzed 1,4-polymerization of 1,3-butadiene: σ-allyl-insertion mechanism versus π-allyl-insertion mechanism

Chemistry - A European Journal

Volumn 8, Issue 20, 2002, Pages 4756-4766

  Tobisch, Sven ^a  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

Allylic compounds; Density functional calculations; Nickel; Polymerization; Reaction mechanisms

Indexed keywords

CATALYSIS; ELECTRONIC STRUCTURE; MONOMERS; POLYMERIZATION; THERMODYNAMICS;

CHEMOSELECTIVITY;

NICKEL COMPOUNDS;

1,3 BUTADIENE; ALLYL COMPOUND; ALLYLNICKEL; MONOMER; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CIS TRANS ISOMERISM; COMPETITION; DENSITY FUNCTIONAL THEORY; ELECTRON; ENERGY TRANSFER; GEOMETRY; KINETICS; POLYMERIZATION; REACTION ANALYSIS; THEORY; THERMODYNAMICS;

EID: 0037131453     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20021018)8:20<4756::AID-CHEM4756>3.0.CO;2-W     Document Type: Article

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