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3743082101
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This value is similar to that reported by Wong for a propene/CO copolymer
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This value is similar to that reported by Wong for a propene/CO copolymer.
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24
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3743128902
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Macromodel, Columbia University, W. Clark Still. We are indebted to Rich Taylor for carrying out these calculations
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Macromodel, Columbia University, W. Clark Still. We are indebted to Rich Taylor for carrying out these calculations.
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27
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28
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3743104174
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BINAPHOS = (R)-2-(diphenylphosphino)-1,1′-binaphthalen-2-yl (S)-1,1′-binaphthalene-2,2′-diyl phosphite
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BINAPHOS = (R)-2-(diphenylphosphino)-1,1′-binaphthalen-2-yl (S)-1,1′-binaphthalene-2,2′-diyl phosphite.
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29
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33748227070
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Batistini, A.; Consiglio, G.; Suter, U. W. Angew. Chem., Int. Ed. Engl. 1992, 31, 303-305.
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Batistini, A.1
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30
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3743108707
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note
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Similar analysis of the transition state leading to 7 is less clear. A 2,1-insertion from intermediate 6 appears strained, but possible. Nevertheless, the presence or absence of 7-membered rings would not change our conclusions regarding the regioselectivity of the initial insertion reaction.
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31
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3743073098
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note
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Consiglio has also observed highly regioselective copolymerizations of α olefins in the presence of the 1,3-bis(diethylphosphino)propane and has attributed the high regioselectivity to the more highly electron-donating dialkylphosphine ligands.
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32
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0001865675
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Tani, K.; Tanigawa, E.; Tatsuno, Y.; Otsuka, S. J. Organomet. Chem. 1985, 279, 87.
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Tani, K.1
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Otsuka, S.4
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