Stepwise assembly of [(C5H5)4(C5Me5)4Co4Rh4(CN)12]4+, an 'organometallic box'

Angewandte Chemie - International Edition

Volumn 37, Issue 12, 1998, Pages 1694-1696

  Klausmeyer, Kevin K ^a   Rauchfuss, Thomas B ^a   Wilson, Scott R ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

Cage compounds; Cobalt; Coordination chemistry; Cyanide; Rhodium

Indexed keywords

EID: 0032479253     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980703)37:12<1694::AID-ANIE1694>3.0.CO;2-0     Document Type: Article

References (29)

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19. [5]): a) Miscellanea Berolinensea ad inrementum scientarium, Berlin, 1710, 1, 377c; b) C. Brown, Philos. Trans. R. Soc. London 1724, 33, 17; c) P. J. Macquer, Mem. Math. Phys. 1752, 2, 87. Prussian Blue has a rather complex structure owing to the presence of defects; see F. Herren, P. Fischer, A. Ludi, W. Halg, Inorg. Chem. 1980, 19, 956.
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22. - (M = Ir, Rh) will be presented elsewhere: S. E. Contakes, K. K. Klausmeyer, T. B. Rauchfuss, unpublished results.
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27. The boxes 6 and 6′ can also be prepared by eight-component condensations of the monometallic precursors (s. Contakes, unpublished results).
28. 2 = 0.0968.
29. 6 counterions are disordered. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101 173. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).