Using carbon-14 isotope tracing to investigate molecular structure effects of the oxygenate dibutyl maleate on soot emissions from a di diesel engine

SAE Technical Papers

Volumn , Issue , 2004, Pages

  Buchholz, Bruce A ^a   Mueller, Charles J ^b   Upatnieks, Ansis ^b   Martin, Glen C ^b   Pitz, William J ^a   Westbrook, Charles K ^a  

^a LAWRENCE LIVERMORE NATIONAL LABORATORY   (United States)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CARBON; CARBON DIOXIDE; COMBUSTION; DUST; ENGINE CYLINDERS; FUELS; ISOTOPES; KINETIC THEORY; MASS SPECTROMETRY; MOLECULAR STRUCTURE; SOOT;

ACCELERATOR MASS SPECTROMETRY; CHEMICAL KINETIC MODEL; COMBUSTION PRO-CESS; DI DIESEL ENGINE; ENGINE EMISSION; MOLECULAR STRUCTURE EFFECTS; PARTICULATE MATTER; SOOT FORMATIONS;

DIESEL ENGINES;

EID: 85072419071     PISSN: 01487191     EISSN: 26883627     Source Type: Journal    
DOI: 10.4271/2004-01-1849     Document Type: Conference Paper

References (38)

1. x High Thermal Efficiency, and Low Noise Diesel Combustion with Oxygenated Agents as Main Fuel," SAE Paper 980506, SAE Trans. 107, Sect. 4, pp. 171-177, 1998.
2. Curran, H.J., Fisher E.M., Glaude P.A., Marinov N.M., Pitz W.J., Westbrook C.K., Layton D.W., Flynn P.F., Durrett R.P., zur Loye A.O., Akinyemi O.C., and Dryer F.L., "Detailed Chemical Kinetic Modeling of Diesel Combustion with Oxygenated Fuels," SAE Paper 2001-01-0653, SAE Trans. 110 2001.
3. Musculus, M.P., Dec J.E., and Tree D.R., "Effects of Fuel Parameters and Diffusion Flame Lift-Off on Soot Formation in a Heavy-Duty Diesel Engine," SAE Paper 2002-01-0889, SAE Trans. 111, Sect. 3, 2002.
4. Choi, C.Y., and Reitz R.D., "An Experimental Study on the Effects of Oxygenated Fuel Blends and Multiple Injection Strategies on DI Diesel Engine Emissions," Fuel, 78: 1303-1317, 1999.
5. Flynn, P.F., Durrett R.P., Hunter G.L., zur Loye A.O., Akinyemi O.C., Dec J.E., and Westbrook C.K., "An Integrated View Combining Laser Diagnostics, Chemical Kinetics, and Emperical Validation," SAE Paper 1999-01-0509, SAE Trans. 108, Sect 3, 1999.
6. Mueller, C.J., Pitz W.J., Pickett L.M., Martin G.C., Siebers D.L., and Westbrook C.K., "Effects of Oxygenates on Soot Processes in DI Disel Engines: Experiments and Numerical Simulations," SAE Paper 2003-01-1791, 2003.
7. Fleisch, T., McCarthy C., Basu A., Udovich C., Charbonneau P., Slodowske W., Mikkelsen S.,. and McCandless J., "A New Clean Diesel Technology: Demonstration of ULEV Emissions on a Navistar Diesel Engine Fueled with Dimethyl Ether," SAE Paper 950061, SAE Trans. 104, Sect. 4, 1995.
8. McCormick, R.L., Ross J.D., and Graboski M.S., "Effect of Several Oxygenates on Regulated Emissions from Heavy-Duty Diesel Engines," Environ. Sci. Tech., 31: 144-1150, 1997.
9. Cheng, A.S., and Dibble R.W., "Emissions Performance of Oxygenate-in-Diesel Blends and Fischer-Tropsch Diesel in a Compression Ignition Engine," SAE Paper 1999-01-3606, 1999.
10. Gonzalez, M.A., Piel W.J., Asmus T.W., Clark W., Garbak J.A., Liney E., Natarajan M., Naegeli D.W., Yost D., Frame E.A., and Wallace J.P. III, "Screening for Advanced Petroleum-Based Diesel Fuels: Part 2-The Effect of Oxygenate Blending Compounds on Exhaust Emissions," SAE Paper 2001-01-3632, SAE Trans. 110, 2001.
11. Maricq, M.M., Chase R.E., Podsiadilik D.H., Siegel W.O., and Kaiser E.W., "The Effect of Dimethoxy Methane Additive on Diesel Vehicle Particulate Emissions," SAE Paper 982572, SAE Trans. 107, Sect. 4, 1998.
12. Bertoli, C., Del Giacomo N., and Beatrice C., "Diesel Combustion Improvements by the Use of Oxygenated Synthetic Fuels," SAE Paper 972972, SAE Trans. 106, Sect. 3, 1997.
13. Liotta, F.J., and Montalvo D.M., "The Effect of Oxygenated Fuels on Emissions from a Modern Heavy-Duty Diesel Engine," SAE Paper 932734, SAE Trans. 102, Sect. 4, 1993.
14. Wang, W.G., Lyons D.W., Clark N.N., Gautam M., and Norton P.M., "Emissions from Nine Heavy Duty Trucks by Diesel and Biodiesel Blend without Engine Modification," Environ. Sci Tech. 34: 933-939, 2000. (Pubitemid 30155193)
15. Buchholz, B.A., Cheng A.S., Dibble R.W., Mueller C.J., and Martin G.C., "Isotope Tracing of Fuel Component Carbon in the Emissions from Diesel Engines," SAE Paper 2002-01-1942, SAE Trans. 111, 927-938, 2002.
16. Mueller, C.J., and Martin G.C., "Effects of Oxygenated Compounds on Combustion and Soot Evolution in a DI Diesel Engine: Broadband Natural Luminosity Imaging," SAE Paper 2002-01-1631, SAE Trans. 111, Sect. 4, 2002.
17. Stoner, M., and Litzinger T.A., "Effects of Structure and Boiling Point of Oxygenated Compounds in Reducing Diesel Emissions," SAE Paper 1999-01-1475, 1999.
18. Cheng, A.S., Buchholz B.A., and Dibble R.W., "The Effect of Oxygenates on Diesel Engine Particulate Matter," SAE Paper 2002-01-1705, 2002.
19. Siebers, D.L., "Liquid-Phase Fuel Penetration in Diesel Sprays," SAE Paper 980809, SAE Trans. 107, Sect. 3, 1998.
20. Higgins, B.S., Mueller C.J., and Siebers D.L., "Measurements of Fuel Effects on Liquid-Phase Penetration of DI Sprays," SAE Paper 1999-01-0519, SAE Trans. 108, Sect. 3, 1999.
21. Siebers, D.L., and Higgins B.S., "Flame Lift-Off on Direct-Injection Diesel Sprays Under Quiescent Conditions," SAE Paper 2001-01-0530, SAE Trans. 110, 2001.
22. Higgins, B.S., and Siebers D.L., "Measurement of the Flame Lift-Off Location on DI Diesel Sprays Using OH Chemiluminescence," SAE Paper 2001-01-0918, SAE Trans. 110, 2001.
23. Dec, J.E., "A Conceptual Model of DI Diesel Combustion Based on Laser-Sheet Imaging," SAE Paper 970873, SAE Trans. 106, Sect. 3, pp. 1319-1348, 1997.
24. Homan, H.S., and Robbins W.K., "A Carbon-14 Tracer Study of the Relative Fractions of Various Fuel Carbons in Soot," Combust. Flame 63: 177-190, 1986.
25. Schmeider, R.W., "Radiotracer Studies of Soot Formation in Diffusion Flames," Proc. Combust. Inst., 20: 1025-1033, 1984.
26. Roberts M.L., Bench G.S., Brown T.A., Caffee M.W., Finkel R.C., Freeman S.P., Hainsworth L.J., Kashgarian M., McAninch J.E., Proctor I.D., Southon J.R., and Vogel J.S., "The LLNL AMS Facility," Nucl. Instru. Meth. B, 123: 57-61, 1997. (Pubitemid 127413499)
27. Vogel, J.S., Southon J.R., Nelson D.E., "Catalyst and Binder Effects in the Use of Filamentous Graphite for AMS," Nucl. Instrum. Methods Phys. Res. Sect. B, 29: 50-56, 1987. (Pubitemid 18553851)
28. Vogel, J.S., Turteltaub K.W., Finkel R., and Nelson D.E., "Accelerator Mass Spectrometry-Isotope Quantification at Attomole Sensitivity," Anal. Chem. 67: A353-A359, 1995.
29. Buchholz, B.A., Mueller C.J., Martin G.C., Cheng A.S., Dibble R.W., Frantz B.R., "Tracing Fuel Component Carbon in the Emissions From Diesel Engines," Nucl. Instrum. Methods Phys. Res. Sect. B (in press), 2004.
30. Mueller, C.J., and Musculus M.P., "Glow Plug Assisted Ignition and Combustion of Methanol in an Optical DI Diesel Engine," SAE Paper 2001-01-2004, 2001.
31. Yokota, H., Kudo Y., Nakajima H., Kakegawa T., and Suzuki T., "A New Concept for Low Emission Diesel Combustion," SAE Paper 970891, SAE Trans. 106, Sect. 3, 1997.
32. Akagawa, H., Miyamoto T., Harada A., Sasaki S., Shimazaki N., Hashizume T., and Tsujimura K., "Approaches to Solve Problems of the Premixed Lean Diesel Combustion," SAE Paper 1999-01-0183, SAE Trans. 108, Sect. 3, 1999.
33. Iwabuchi, Y., Kawai K., Shoji T., and Takeda Y., "Trial of New Concept Diesel Combustion System-Premixed Compression-Ignited Combustion," SAE Paper 1999-01-0185, SAE Trans. 108, Sect. 3, 1999.
34. Mueller, C.J., Martin G.C., Briggs T.E., and Duffy K.P., "An Experimental Investigation of In-Cylinder Processes under Dual-Injection Conditions in a DI Diesel Engine," SAE Paper 2004-01-1843, 2004.
35. Ehmann, W.D., and Vance D.E., Chap. 10, "Radiotracer Methods" in Radiochemistry and Nuclear Methods of Analysis, John Wiley & Sons, Inc., New York, 1991.
36. Friedlander G., and Kennedy J.W., Chap. 11, "Tracers in Chemical Applications" in Nuclear and Radiochemistry, John Wiley & Sons, Inc., New York, 1955.
37. Fisher, E.M., Pitz W.J., Curran H.J., and Westbrook C.K., "Detailed Chemical Kinetic Mechanisms for the Combustion of Oxygenated Fuels," Proc. Combust. Inst., 28: 1579-1586, 2000.
38. Bozzelli, J.W., and Chen C.-J., New Jersey Institute of Technology, Newark, NJ, C-H bond strengths in esters estimated using CBS-Q calculations with corrections from isodesmic reactions, personal communication, 1999.