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The easily reduced nitro, aldehyde and ketone functionalities were hydrosilylated under these conditions.
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The easily reduced nitro, aldehyde and ketone functionalities were hydrosilylated under these conditions.
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The quenching with NH4F(aq) during workup was found to be detrimental to the isolated yield; thus, this step was omitted. Clean product was still observed by 1H and 13C NMR spectroscopy. This brought doubt over the necessity of this step for the general procedure, after initially assuming it ridded the system of excess silane that jeopardises later purification.
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