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Angewandte Chemie - International Edition

Volumn 54, Issue 19, 2015, Pages 5722-5726

A stable but highly reactive phosphine-coordinated borenium: Metal-free dihydrogen activation and alkyne 1,2-carboboration

(5) Devillard, Marc a Brousses, Rémy b Miqueu, Karinne c Bouhadir, Ghenwa a Bourissou, Didier a

a UNIVERSITÉ PAUL SABATIER (France)

b Université Paul Sabatier (France)

c UNIVERSITÉ DE PAU ET DES PAYS DE L'ADOUR (France)

Author keywords

borenium cations; density functional calculations; frustrated Lewis pairs; H2 activation; phosphorus

Indexed keywords

CHEMICAL ACTIVATION; DENSITY FUNCTIONAL THEORY; NAPHTHALENE; PHOSPHORUS; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL);

BOND CLEAVAGES; BRIDGE SUPPORTS; DEUTERIUM LABELING; DFT CALCULATION; ELECTROPHILICITY; FRUSTRATED LEWIS PAIRS; HETEROLYTIC SPLITTING; METAL FREE;

POSITIVE IONS;

EID: 85027953282 PISSN: 14337851 EISSN: 15213773 Source Type: Journal
DOI: 10.1002/anie.201500959 Document Type: Article

Times cited : (80)

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