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Selected examples of intermolecular reactions:.
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PdII‐assisted intermolecular dialkylation and alkylation/acylation:.
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Transition‐metal‐catalyzed cyclization:.
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Selected recent examples of cycloaddition reactions utilizing enamines:.
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85128591376
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In the umpolung β‐phenylation of N‐alkoxyenamine, the use of 2‐methylpropanal as α‐branched aldehyde led to the α‐phenylated aldehyde in 46 % yield.
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In the umpolung β‐phenylation of N‐alkoxyenamine, the use of 2‐methylpropanal as α‐branched aldehyde led to the α‐phenylated aldehyde in 46 % yield.
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59
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85128682339
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The relative configuration of threo‐7e (major diastereomer) was determined by converting threo‐7e into authentic cis‐15 (see the Supporting Information).
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The relative configuration of threo‐7e (major diastereomer) was determined by converting threo‐7e into authentic cis‐15 (see the Supporting Information).
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