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Volumn 20, Issue 39, 2014, Pages 12416-12420

Thermochromic Luminescent Nest-Like Silver Thiolate Cluster

Author keywords

cluster compounds; nest like structures; silver; template synthesis; thermochromism

Indexed keywords

CRYSTAL STRUCTURE; LUMINESCENCE; NEGATIVE IONS; RED SHIFT; SILVER; SINGLE CRYSTALS;

EID: 84982311266     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201404049     Document Type: Article
Times cited : (134)

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    • Crystal data for 1 (298 K) C, H, Ag, F, N, O, S, a, =15.4747, b, =32.8095(18),, c, =19.260(2) Å,, =113.612(15)°,, V, =8960.0(14) Å, space group, P, 2, m, Z, =2, 32323 reflections measured, 15614 unique (, R, =0.1191), final, R, =0.1240,, wR, =0.2867 for, I, >2, I,). Crystal data for 1 (200 K) C, H, Ag, F, N, O, S, a, =15.3802(3),, b, =32.6838(7),, c, =19.0724(3) Å,, =113.547(2)°,, V, =8789.1(3) Å, space group, P, 2, m, Z, =2, 31999 reflections measured, 15331 unique (, R, =0.0304), final, R, =0.0988,, wR, =0.2610 for, I, >2, I,). Crystal data for 1 (110 K) C, H, Ag, F, N, O, S, a, =15.2733(7),, b, =32.4408(10),, c, =18.9495(9) Å,, =113.670(6)°,, V, =8599.2(6) Å, space group, P, 2, m, Z, =2, 31619 reflections measured, 15015 unique (, R, =0.0351), final, R, =0.0967,, wR, =0.2736 for, I, >2, I,). Crystal data for 2 (298 K) C, H, Ag, N, O, S, a, =13.5002(5),, b, =27.6792(9),, c, =19.5327(10) Å,, =93.725(4)°,, V, =7283.5(5) Å, space group, P, 2, Z, =2, 54133 reflections measured, 22215 unique (, R, =0.0751), final, R, =0.1139,, wR, =0.2790 for, I, >2, I,). Crystal data for 2 (200 K) C, H, Ag, N, O, S, a, =13.4287(6),, b, =27.6779(18),, c, =19.6339(12) Å,, =94.019(4)°,, V, =7279.5(7) Å, space group, P, 2, Z, =2, 28264 reflections measured, 20667 unique (, R, =0.0707), final, R, =0.0994,, wR, =0.1786 for, I, >2, I,). Crystal data for 2 (110 K) C, H, Ag, N, O, S, a, =13.2802(2),, b, =27.5371(3),, c, =19.3861(3) Å,, =95.0740(10)°,, V, =7061.68(17) Å, space group, P, 2, Z, =2, 48472 reflections measured, 23153 unique (, R, =0.0397), final, R, =0.0774,, wR, =0.2204 for, I, >2, I,). CCDC 995741 (1, 110 K), 995742 (1, 200 K), 995743 (1, 298 K), 995744 (2, 110 K), 995745 (2, 200 K)995746 (2, 298 K) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif
    • Crystal data for 1 (298 K): C86H150Ag33F27N4O24S19, a=15.4747(16), b=32.8095(18), c=19.260(2) Å, β=113.612(15)°, V=8960.0(14) Å3, space group P21/m, Z=2, 32323 reflections measured, 15614 unique (Rint=0.1191), final R1=0.1240, wR2=0.2867 for I>2σ(I). Crystal data for 1 (200 K): C86H150Ag33F27N4O24S19, a=15.3802(3), b=32.6838(7), c=19.0724(3) Å, β=113.547(2)°, V=8789.1(3) Å3, space group P21/m, Z=2, 31999 reflections measured, 15331 unique (Rint=0.0304), final R1=0.0988, wR2=0.2610 for I>2σ(I). Crystal data for 1 (110 K): C86H150Ag33F27N4O24S19, a=15.2733(7), b=32.4408(10), c=18.9495(9) Å, β=113.670(6)°, V=8599.2(6) Å3, space group P21/m, Z=2, 31619 reflections measured, 15015 unique (Rint=0.0351), final R1=0.0967, wR2=0.2736 for I>2σ(I). Crystal data for 2 (298 K): C68H150Ag31N11O27S19, a=13.5002(5), b=27.6792(9), c=19.5327(10) Å, β=93.725(4)°, V=7283.5(5) Å3, space group P21, Z=2, 54133 reflections measured, 22215 unique (Rint=0.0751), final R1=0.1139, wR2=0.2790 for I>2σ(I). Crystal data for 2 (200 K): C68H150Ag31N11O27S19, a=13.4287(6), b=27.6779(18), c=19.6339(12) Å, β=94.019(4)°, V=7279.5(7) Å3, space group P21, Z=2, 28264 reflections measured, 20667 unique (Rint=0.0707), final R1=0.0994, wR2=0.1786 for I>2σ(I). Crystal data for 2 (110 K): C68H150Ag31N11O27S19, a=13.2802(2), b=27.5371(3), c=19.3861(3) Å, β=95.0740(10)°, V=7061.68(17) Å3, space group P21, Z=2, 48472 reflections measured, 23153 unique (Rint=0.0397), final R1=0.0774, wR2=0.2204 for I>2σ(I). CCDC 995741 (1, 110 K), 995742 (1, 200 K), 995743 (1, 298 K), 995744 (2, 110 K), 995745 (2, 200 K), and 995746 (2, 298 K) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
    • , Issue.16


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.