A giant silver alkynyl cage with sixty silver(I) ions clustered around polyoxometalate templates

Angewandte Chemie - International Edition

Volumn 49, Issue 10, 2010, Pages 1765-1767

  Qiao, Juan ^a   Shi, Kang ^a   Wang, Quan Ming ^a  

^a XIAMEN UNIVERSITY   (China)

Author keywords

Alkynyl ligands; Cluster compounds; Polyoxometalates; Silver; Template synthesis

Indexed keywords

ALKYNYL LIGANDS; ALKYNYLS; CLUSTER COMPOUNDS; CORE/SHELL; ELECTROCHEMICAL STUDIES; POLYOXOMETALATES; REDOX BUFFER; SOLVOTHERMAL CONDITIONS; TEMPLATE SYNTHESIS;

CHELATION; COMPLEXATION; LIGANDS; SILVER COMPOUNDS;

SYNTHESIS (CHEMICAL);

EID: 77749283479     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.200906815     Document Type: Article

References (33)

1. S. Anderson, H. L. Anderson, J. K. M. Sanders, Acc. Chem. Res. 1993, 26, 469-475.
2. a) P. D. Beer, P. A. Gale, Angew. Chem. 2001, 113, 502-532;
3. Angew. Chem. Int. Ed. 2001, 40, 486-516;
4. b) P. A. Gale, Coord. Chem. Rev. 2000, 199, 181;
5. c) P. A. Gale, Coord. Chem. Rev. 2001, 213, 79.
6. a) R. Vilar, Angew. Chem. 2003, 115, 1498-1516;
7. Angew. Chem. Int. Ed. 2003, 42, 1460-1477;
8. b) R. Vilar, Eur. J. Inorg. Chem. 2008, 357.
9. a) D. Rais, J. Yau, D. M. P. Mingos, R. Vilar, A. J. P. White, D. J. Williams, Angew. Chem. 2001, 113, 3572-3575;
10. Angew. Chem. Int. Ed. 2001, 40, 3464-3467;
11. b) G. G. Gao, P.-S. Cheng, T. C. W. Mak, J. Am. Chem. Soc. 2009, 131, 18257-18259.
12. S.-D. Bian, H.-B. Wu, Q.-M. Wang, Angew. Chem. 2009, 121, 5467-5469;
13. Angew. Chem. Int. Ed. 2009, 48, 5363-5365.
14. a) S.-D. Bian, Q.-M. Wang, Chem. Commun. 2008, 5586-5588;
15. b) S.-D. Bian, J.-H. Jia, Q.-M. Wang, J. Am. Chem. Soc. 2009, 131, 3422-3423.
16. Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications (Eds.: M. T. Pope, A. Müller), Kluwer, Dor- drecht, 2001.
17. a) E. Coronado, C. J. Gómez-García, Chem. Rev. 1998, 98, 273- 296;
18. b) W. G. Klemperer, C. G. Wall, Chem. Rev. 1998, 98, 297-306.
19. a) A. Müller, S. Q. N. Shah, H. Bögge, Nature 1999, 397, 48-50;
20. b) D.-L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 2007, 36, 105-121.
21. a) C. Streb, C. Ritchie, D.-L. Long, P. Kögerler, L. Cronin, Angew. Chem. 2007, 119, 7723-7726;
22. Angew. Chem. Int. Ed. 2007, 46, 7579-7582;
23. b) J. T. Rhule, W. A. Neiwert, K. I. Hardcastle, B. T. Do, C. L. Hill, J. Am. Chem. Soc. 2001, 123, 12101-12102;
24. c) H. I. S. Nogueira, F. A. A. Paz, P. A. F. Teix- eira, J. Klinowski, Chem. Commun. 2006, 2953-2955.
25. int = 0.0659), final Rl= 0.0557, wR2 = 0.1232 for 20123 observed reflections [I>2σ(I)]. CCDC 756502 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www. ccdc.cam.ac.uk/data-request/cif.
26. a) V. Balraj, K. Vidyasagar, Inorg. Chem. 1999, 38, 1394-1400;
27. b) J.-P. Wang, X.-D. Du, J.-Y. Niu, J. Solid State Chem. 2006, 179, 3260-3264;
28. c) L.-M. Dai, E.-B. Wang, W.-S. You, Z.-M. Zhang, J. Cluster Sci. 2008, 19, 511-519.
29. dmso: dimethylsulfoxide; Y.-F. Song, H. Abbas, C. Ritchie, N. McMillian, D.-L. Long, N. Gadegaard, L. Cronin, J. Mater. Chem. 2007, 17, 1903-1908.
30. E. F. Wilson, H. Abbas, B. J. Duncombe, C. Streb, D.-L. Long, L. Cronin, J. Am. Chem. Soc. 2008, 130, 13876-13884.
31. a) B. Q. Huang, L. Wang, K. Shi, Z. X. Xie, L. S. Zheng, J. Electroanal. Chem. 2008, 615, 19-24;
32. b) B. Keita, L. Nadjo, J. Electroanal. Chem. 1988, 247, 157-161.
33. L. Yuan, C. Qin, X. L. Wang, Y. G. Li, E. B. Wang, Dalton Trans. 2009, 4169-4175.